The paper includes the TG-DTG thermogravimetric air-testing of a cellulose mixture modified with the additives of expanded vermiculite or expanded perlite. A thermal degradation test was carried out at 1000°C with a simultaneous qualitative analysis of the emitted gases. During the thermal degradation process, the thermal effects were also measured. The research results indicate that expanded vermiculite or expanded perlite do not emit toxic gases during thermal degradation. The cellulose mixture modification, with the additives of expanded vermiculite or perlite, does not result in the creation of new gaseous compounds in the process of thermal degradation. A s investigated below, the mixtures tested in this article find application in gating systems for supplying liquid metal in no-bake moulds. Such cellulose-based material solutions shall allow the foundry industry to introduce less gas vaporising technologies within the entire casting production process.
This paper presents the findings of a study of gas emissivity and the volumetric gas flow rate from a patented modified cellulose mix used in production of disposable sand casting moulds. The modified cellulose mix with such additives as expanded perlite, expanded vermiculite and microspheres was used as the study material. The results for gas emissivity and the gas flow rate for the modified cellulose mix were compared with the gas emissivity of the commercial material used in gating systems in disposable sand casting moulds. The results have shown that the modified cellulose mix is characterized by a lower gas emissivity by as much as 50% and lower gas flow rate per unit mass during the process of thermal degradation at the temperature of 900°C, compared to the commercial mix. It was also noted that the amount of microspheres considerably affected the amount of gas produced.
The herein paper contains the results of investigations on a new type of cellulose blend used for the manufacture of profiles applied in the process of making gating systems in the foundry industry. A standard cellulose profile was subjected to an experiment. During the experiment the profile was filled with a liquid cast iron and at the same time the temperatures of the liquid metal crystallizing inside the profile were measured as well as the temperature of the outer layer of the profile was controlled. Further, the microstructure of the cast iron, which crystallized out inside the cellulose profile, was analysed and the cellulose, thermally degraded after the experiment, was verified with the use of the chemical analysis method. Moreover, a quality analysis of the original as well as the degraded cellulose profile was run with the use of the FTIR infrared spectroscopy. The presented results revealed that the cellulose blend is aluminium silicate enriched and contains organic binder additives. The cast iron, which crystallized out, tended to have an equilibrium pearlitic structure with the release of graphite and carbides. The generation of disequilibrium ausferrite phases was also observed in the structure.