In sand moulds, at a distance of 3 mm from the metal- mould interface, the sensors of temperature, and of oxygen and hydrogen content were installed. Temperature and the evolution of partial gas pressure have been analysed in moulds bonded with bentonite with or without the addition of seacoal, water glass or furan resin. Moulds were poured with ductile iron. For comparison, also tests with the grey iron have been executed. It was found that the gas atmosphere near the interface depends mainly on the content of a carbonaceous substance in the mould. In the green sand moulds with 5% of seacoal or bonded with furan resin, after the mould filling, a sudden increase in the hydrogen content and the drop of oxygen is observed. This gas evolution results from the oxidation of carbon and reduction of water vapour in the mould material, and also from the reduction of water vapour and alloy reoxidation. In carbon-free sand, the evolution in the gas composition is slower because water vapour is reduced only at the interface. Changes of oxygen and hydrogen content in the controlled zone are determined by the transport phenomena.
The new investigation method of the kinetics of the gas emission from moulding sands used for moulds and cores is presented in this paper. The gas evolution rate is presented not only as a function of heating time but also as a function of instantaneous temperatures. In relation to the time and heating temperature the oxygen and hydrogen contents in evolving gases was also measured. This method was developed in the Laboratory of Foundry Moulds Technology, Faculty of Foundry Engineering, AGH. Gas amounts which are emitted from the moulding sand at the given temperature recalculated to the time unit (kinetics) are obtained in investigations. Results of investigations of moulding sand with furan resin are presented - as an example - in the paper.