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Abstract

An analysis has been carried out of the influence of annealing time at the preheating temperature of 650 °C on the change in hardness and alloy structure of lamellar graphite cast iron in the working as well as in the laboratory conditions. This preheat temperature is common during reclaiming welding of castings with complex shapes. The changes in unalloyed cast iron EN-GJL 200 to EN-GJL 300 according to ISO 1690 standard and cast iron with low amount of elements such as Sn, Cu, Cr, and Mo and their combinations were assessed. It was found that the cast iron of higher strength grades has better hardness and structural stability. Cast iron alloyed with chromium or its combinations has the highest stability. In unalloyed cast iron, a partial degradation of pearlite occurs; in alloyed cast iron the structural changes are not conclusive.
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Abstract

The subject of the paper is structural stability of the Zn-26 wt.% Al binary alloys doped with 2.2 wt.% Cu or 1.6 wt.% Ti addition. The structural stability of Zn-Al alloys with increased Al content is connected with stability of solid solution of zinc in aluminium α', which is the main component of these alloys microstructure. Such a solution undergoes phase transformations which are accompanied, among others, by changes in dimensions and strength properties. The structural stability of the ZnAL26Cu2.2 and ZnAl26Ti1.6 alloys was investigated using XRD examinations during long term natural ageing after casting, as well as during long term natural ageing after super-saturation and quenching. On the basis of the performed examinations it was stated that small Ti addition to the binary ZnAl25 alloy, apart from structure refinement, accelerates decomposition of the primary α' phase giving stable structure in a shorter period of time in comparison with the alloy without Ti addition. Addition of Ti in amount of 1.6 wt.%, totally replacing Cu, allows obtaining stable structure and dimensions and allows avoiding structural instability caused by the metastable ε−CuZn4 phase present in the ZnAl26Cu2.2 alloy.
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