According to a fuel flexibility, fluidized bed boilers are considered as appropriate for biomass combustion as cofiring. But the burning of fuels such as forest and agricultural biomass raises a number of operational problems. Most important of these problems are bed agglomeration and deposition. Deposition appears when biomass contains significant amounts of alkali elements, such as sodium and potassium. The purpose of the work is to select a fuel additive to overcome these operational problems. Investigations were conducted in two stages at a pilot scale 0.1 MWth laboratory circulating fluidized bed reactor. As the fuel, the mixture of biomass contained forest residues, sunflower husks, straw and wood pellets from mixed woods was selected. In the first stage biomass was burnt without any additives, while in the second one the fuel was enriched with some additive. The additive (liquid mixture of chemicals) was added to the fuel in amounts of 1 dm3 per 5-10 Mg of fuel. The following operational parameters were examined: temperature profiles along the height of the circulating fluidised bed column, pressure profiles, emissions. After the tests, the laboratory reactor was inspected inside. Its results enables expression of the following conclusions: there was no agglomeration during fuel additive testing, and the deposition was reduced as well. Moreover, the parts (heating surfaces, separator) of the laboratory reactor were coated with a protective layer. The layer covered microcracks and protected the parts from deposition for a long period after the operation.
Petrographic and physico-chemical analyses of ashes are carried out on a large scale and presented in numerous scientific papers. The mentioned ashes are obtained from filters and electrostatic precipitators mounted in large industrial installations. The large-scale analysis of the ashes obtained directly from grate furnaces or blast furnaces mounted in low-power boilers started with combating smog and low-stack emissions. The collection of ash samples from household furnaces usually involves the analysis of the combustion of waste in low-power boilers. This is justified in the case of old type boilers, which were designed to use virtually any fuel. Currently, new types of boilers, designed to burn dedicated fuels, are offered on the market. The aim is to use only renewable fuels (biomass) or fossil fuels with high quality parameters, which are more environment-friendly, e.g. eco-pea coal, lignite briquettes, or peat briquettes. The authors of the study focused on examining the ash obtained from boilers for burning wood pellets by performing microscopic analysis of residues after biomass combustion. The above mentioned analysis provides a comprehensive information on the efficiency of the combustion process, the content of contaminants remaining in the ash, and the suitability of ash for other applications. The entire process, from the moment of collecting the samples to the execution of the analysis takes up to 12 hours, which ensures a quick decision on furnace adjustment or fuel change. The ash components were determined based on the results obtained by the Fly-Ash Working Group of the International Committee for Coal and Organic Petrology (ICCP). The mentioned classification has been supplemented with new key elements occurring in ashes resulting from the combustion of wood pellets in household boilers. This allowed determining the percentage content of characteristic components in the tested material, which can be used as a specific benchmark when issuing opinions on the quality and efficiency of the boiler and the combusted pellets.
On the basis of acoustically registered cross-sections of krill aggregations, regular, irregular and layer forms were distinguished. Regular forms are most frequently observed during spring and in the day time, while irregular forms are most frequent during summer and night hours. The density histograms made for two hour intervals clearly show the day-night difference, but the seasonal (spring, summer) difference is less pronounced. Mean density of swarm is lowest during the night and reaches a maximum in early morning hours. The mean volume backscattering strength values (Sv) for spring and summer are nearly identical. We suggest that regular forms correspond to foraging swarms and irregular forms to feeding swarms as described by Hamner (1984).
24 species of 8 fish families were found to occur on the shelf of Elephant Island during austral spring and summer of 1986/87 season. Notothenia gibberifrons was a predominant species (78—83% per catch). The presence of Champsocephalus gunnari and Chaenocephalus aceratus (15—20% per catch) almost completed fish composition profile. A pronounced decrease of Notothenia rossi (0.03—0.04% per catch) was noticed. Some specimens of Champsocephalus gunnari were characterized by a spawning-time shifted by almost half a year comparing to the remaining part of its population.
The chlorophyll a content was measured at 62 oceanographic stations. At each station samples were collected from eight standard depths between the water surface and 150 m. Integrated values (chlorophyll α mg/m2) are used in the presentation of the results and discussion. The recorded quantities of chlorophyll α were rather high, amounting to as much as 634 mg/m2. The areas with high chlorophyll a content (> 200 mg/m2) were located in the region of the Anvers Island and Brabant Island, on the shelf around Joinville Island and opposite the Antarctic Sound, close to Clarence Island and beyond the regions recommended in the BIOMASS-SIBEX programme to the east and south of the South Orkney Islands. In the acetonie extracts of photosynthetizing pigments large quantities of phytoxanthin were found using the TLC method, what precludes the use of the Lorenzen method for determination of chlorophyll α and its degradation products.
The material discussed in this paper was collected in the Drake Passage and Bransfield Strait (Antarctica) within the framework of the BIOMASS-SIBEX programme. Samples were collected by hauling Nansen nets verticaly through the 100 — 0, 300—100 and 500 — 300 m layers in December 1983 and January 1984. Of the six species recorded — Metaconchoecia isocheira, Alacia hettacra, Alacia belgicae, Metaconchoecia skogsbergi, Boroecia antipoda and Discoconchoecia off. elegans — the first three, endemic to Antarctic waters — were predominant (92.9%). Ostracoda were found most abundantly in the eastern part of the study area — between Elephant Island and South Orkney Islands, and in the south-western part of Bransfield Strait. Their vertical distribution depended on the hydrological conditions. Ostracoda were most numerous in the 500—300 m and 300 — 100 m layers; very few were recorded in the 100—0 m surface layer.
During the BIOMASS-SIBEX Antarctic expedition the distribution of Copepoda in three water layers (0—100, 100—300 and 300—500 m) in the Bransfield Strait and southern Drake Passage was studied. Altogether 46 taxa were recorded (Tabs. 1 and 2); the number of taxa increased with depth. Faunistic differences between the Drake Passage and the Bransfield Strait were observed. In some species the age-related splitting of the populations was registered (Figs. 2, 3 and 4). Young generations occupied usually the upper water layers.
The aim of this study was to compare and analyze the gasification process of beech wood. The experimental investigation was conducted inside a gasifier, which can be operated in downdraft and updraft gasification system. The most important operating parameter studied in this paper was the influence of the amount of supply air on the temperature distribution, biomass consumption and syngas calorific value. The results show that the amount of air significantly influences the temperature in the combustion zone for the downdraft gasification process, where temperature differences reached more than 150 ◦C.The increased amount of air supplied to the gasifier caused an increase in fuel consumption for both experimental setups. Experimental results regarding equivalence ratio show that for value below 0.2, the updraft gasification is characterized by a higher calorific value of producer gas, while for about 0.22 a similar calorific value (6.5 MJ/Nm3) for both gasification configurations was obtained. Above this value, an increase in equivalence ratio causes a decrease in the calorific value of gas for downdraft and updraft gasifiers.
The changes in the domestic solid fuel market (including forecasted increases in the fuel prices) and the growing requirements related to actual environmental standards, result in increased interest in renewable energy sources, such as biomass, wind and solar energy. These sources will allow to achieve reduction in the CO2 emission, and consequently – avoid environmental costs after 2020. Therefore, the development of distributed energy systems, based on the use of biomass boilers, gas boilers and high efficiency combined heat and power units, will enable the fulfillment of current standards in the field of energy efficiency and emission of pollutants to the atmosphere. It should be emphasized that the actions taken to reduce emissions (e.g. anti-smog act) will contribute to reducing coal consumption in the municipal and housing sector (households, agriculture and other customers) in favor of biomass and other renewable energy sources. The article reviews selected biomass technologies: - fluidized, dust and grate boilers, - straw-fired boilers, - cogeneration systems powered by biomass, - torrefaction and biomass carbonisation. The mentioned technologies are characterized by a high potential of in the field of dynamic development and practical application in the coming years. Thus, they can improve difficult situation in the distributed energy sector with a capacity up to 50 MW.
Biomass is one of the most frequently used sources of renewable energy. For centuries, wood has been used by people to heat their homes, and nowadays it is also used to generate electricity. The article discusses legal issues related to biomass, classification of biomass for energy purposes, quality parameters of selected ecological fuels, quality requirements for biomass, as well as biomass trade in the world. The article compares the quality requirements for biomass purchased by individual companies from the power sector (mainly dimensions, calorific value, moisture content, ash content, sulfur and chlorine). An analysis of the price of wood pellets on international markets, represented by the biomass stock exchanges: RBCN, EEX and BALTPOOL was also performed. The market analysis clearly shows that the international market for industrial pellets is dominated by intercontinental trade, which mainly concerns exchanges between the United States of America as a producer and Europe as a consumer. The largest amount of biomass is imported by the United Kingdom, mainly for its Drax biomass power plant, and this biomass comes from the USA and Canada. In addition to Great Britain, significant importers of wood pellets are the Netherlands, Belgium and Denmark. Judging by the interest of Polish energy companies in the purchase of biomass, also in Poland, the development of the biomass market should be expected.
During the SIBEX1' programme in December 1983/January 1984, 27 hauls were made from the "Profesor Siedlecki" with a 368 — mesh midwater sampling trwal. A total of 13 fish species at postlarval or juvenile stages was found in the catches. The greatest aboundance and species diversity of juvenile ichthyofauna was observed within shelf waters of the Peninsula. Postlarval and juvenile Pleuragramma antarcticum was the most common and most aboundant species there.
Hydrological conditions in the region between the King George and Elephant Islands were defined on the basis of 24 STD measurements and 20 XBT profiles made in the time period from 26 October to 16 November 1986. In the entire investigated region the surface water temperature was below zero, often close to freezing point. The presence of summer modification of surface water with its characteristic thermal minimum was not found. Between the Scotia Front and the relatively well pronounced stream of geostrophic currents the anticyclonic meander was observed above the edge of the shelf at the depth of 100 m. Its spread was about 10 nM and within this meander the downwelling of surface water was noticed. As a compensating water movement, the upwelling of warmer waters was observed in the Drake Passage at 400 m.
Zooplankton in the water column from the surface to bottom was studied. Copepods were the dominating organisms. Average zooplankton biomass was about 5 g in 1000 m3 . The highest zooplankton density occurred between 300 and 600 m. The influence of the Scotia Front on the horizontal and vertical distribution of zooplankton is discussed.
The distribution of pelagic Polychaeta in the Scotia Front region is presented. 6 polychaete taxa were recorded in the material with the most abundant Pelagobia longicirrata which constituted 86% of all collected specimens. The mixing of water masses in the frontal zone influence the quantitative distribution of polychaetes in the water column.
In the planktonie material collected using a Nansen net (vertical hauls) larvae of two euphausiid species were found. The dominant and occurring in all stations were larvae of Thysanoessa macrura. Following larval stages were encountered: nauplius, metanauplius, calyptopis I and calyptopis II. The most numerous and occurring in the widest depth spectrum were calyptopes I. Only twice furcilia VI of Euphausia superba were found. The distribution of euphausiid larvae was influenced by the stratification and circulation of water masses in the investigated area.
Results of hydroacoustic investigations of krill biomass carried out in the South Shetland Island region between October 1986 and January 1987 are presented. A considerable difference in the krill biomass between Antarctic spring and summer was recorded. Initially observations were conducted close to Elephant Island, in the period just after the retreated of compact ice cover. Krill then aggregated only in swarms, the density of which frequently exceeded 100 t nM-2 . In the region of Polygon I (30—31 October 1986) the total estimated biomass was 26899 t, in the region of Polygon II (6—10 November 1986) it was 25827 t. Investigations were repeated in January 1987 obtaining 112372 t in the Bransfield Strait and 390309 t in the region of Elephant Island. The results are presented in tables and maps.
On the basis of hydroacoustic observations it is shown that migrations of krill during spring are stronger than during summer. Migrations of krill are described by the function: H(t) = A + Bcos((2ᴨt/T + φ ) + C c o s ( 2 ᴨt/T + φ ), where: H is depth of the mass center of krill biomass, A — mean depth of krill occurrence, В — amplitude of migrations with period T! = 24 h, С — amplitude of migrations with period T2 = 12 h, (φ1, φ2 — phases of migration process with T, = 24 and T2 = 12 hours. Parameters of the equation are the following: spring — A = 62.2 m, В = 19.5 m, С = 4.6 m, φ1 = 0.1 h, φ2 = 0 . 1 5 h; summer — A = 75.8 m, В = 0.5 m, С = 3.6 m, φ1 = 1.8 h, φ2 = 6.4 h.
In the region of the Admiralty Bay 12 nesting bird species were encountered of a total abundance of 40890 pairs and biomass amounting to about 395000 kg Three penguin species constituted 91.7% in abundance, their biomass constituting 98.7% of the whole community. Densities of abundance and biomass of adult birds in relation to the living area of penguins (i.e. 775 km2) ranged from 32.3 to 121.4 indiv. km-2 and from 115.1 to 4730 kg k m-2.
One of the elements of the Polish Energy Policy program is the development of renewable energy, including energy from biomass combustion. In Poland, the Green Block was built at the Połaniec Power Station fired with 100% biomass fuel. This solution is conducive not only to obtaining energy but also to improving environmental protection. During the combustion of biomass in a fluidized bed boiler, about 50 thousand tons of fly ash per year being a source of nutrients for plants, for example potassium salts, phosphorus, calcium, boron compounds, etc. was derived. The subject of the research were three types of ashes from biomass combustion containing 80% dendromass and 20% agromass. Agromas was made of straw, dried material or sliced palm nuts. The physical characteristics and chemical composition of three basic fly ash samples are presented. Due to the high fineness and thus dusting during spreading, it was found that there is no possibility of the direct use of fly ash from biomass combustion as an alkalizing agent for acidic soils. The lowest bulk density was demonstrated by samples of fly ash originating from the combustion of biomass containing 20% straw as agromass, while the poorest in potassium and phosphorus were ash samples obtained from the combustion of biomass containing 20% agromass in the form of palm kernel slate. As additional components, mineral acids as well as inorganic compounds, including industrial waste, were used to correct the chemical composition and to mineral fertilizer granulation. The number of introduced components was related to the postulated composition of the produced fertilizer. Examples of mineral fertilizers obtained, both simple and multicomponent fertilizers, are presented.
The aim of the paper is a comparative study of co-firing high shares of wooden and agro-biomass with hard coal under oxy-fuel and air conditions in the laboratory scale reactor for pulverised fuels. The investigations of co-combustion behaviour NOx and SO2 emission and burnout were carried out for selected blends. Detailed investigations were concentrated on determining the effect of dosing oxygen method into the burner on NOx emission. The paper presents the results of co-firing blends with 20 and 50% share of biomass by mass in air and oxy-combustion condition. Biomass oxy-cofiring integrated with CCS (CO2 capture) technology could be a carbon negative technology. The reduction of NOx emissions in the conditions of oxy-co-firing is dependent on the concentration of oxygen in the primary stream of oxidiser. A significant reduction of NOx was achieved in the case of low oxygen concentration in the primary stream for each investigated blends. Co-firing of biomass with coal in an oxygen enriched atmosphere enhances combustion behaviour, lowers fuel burnout and as a result increases of the boiler efficiency.
Preliminary lab-scale investigations were conducted on slagging abatement in biomass-firing by fuel mixing. Three agriculture biomass fuels and olive cake were used in the experiments. Polish lignites and bituminous coals were examined as anti-sintering additives. The effects of chlorine release, potassium retention and ash sintering were examined by heating samples of biomass fuels and additives in the muffle oven and, next, firing them in the laboratory down-fired furnace at the temperature in the range of 800-1150ºC. The obtained slag samples were analysed on: chlorine and potassium content, sintering tendency and crystalline components. Among the examined coals lignite from Turów mine and bituminous coal from Bolesław Śmiały mine appeared to be the most effective in potassium retention in aluminosilicate and chlorine release from slag. Possibly the major factor of these coals which reduced ash sintering was relatively high content of kaolinite
The use of biomass in the energy industry is the consequence of ongoing efforts to replace Energy from fossil fuels with energy from renewable sources. However, due to the diversity of the biomass, its use as a solid fuel generates waste with diverse and unstable chemical composition. Waste from biomass combustion is a raw material with a very diverse composition, even in the case of using only one type of biomass. The content of individual elements in fly ash from the combustion of biomass ranges from zero to tens of percent. This makes it difficult to determine the optimal recovery methods. The ashes from the combustion of biomass are most commonly used in the production of building materials and agriculture. This article presents the elemental composition of the most commonly used biomass fuels. The results of the analysis of elemental composition of fly ashes from the combustion of forest and agricultural biomass in fluidized bed boilers used in the commercial power industry were presented. These ashes are characterized by a high content of calcium (12.3–19.4%), silicon (1.2–8.3%), potassium (0.05–1.46%), chlorine (1.1–6.1%), and iron (0.8–6.5%). The discussed ashes contained no sodium. Aluminum was found only in one of the five ashes. Manganese, chromium, copper, nickel, lead, zinc, sulfur, bismuth, titanium and zirconium were found in all of the examined ashes. The analysis of elemental composition may allow for a preliminary assessment of the recovery potential of a given ash.
Poland is now faced with the task of developing a long-term energy policy for decades to come, a strategy capable of reconciling the security of power supplies as well as effective economic processes, ensuring adequate standards of environmental protection. The process in which fossil fuels are converted into energy carriers of choice is accompanied by the emission of various gas substances which escape into the environment. Later on, those substances accumulate in the atmosphere as greenhouse gases affecting the Earth’s radiation balance – the greenhouse effect. Upsetting the balance between emission levels of those gases and the capacity to convert them in the atmosphere is the reason for climate changes. Sustainable development indices constitute a monitoring tool which makes it possible to create a statistical image of a country from the perspective of a new development paradigm. The most important feature of this index is the capability of comparing values, enabling to determine the position of a given object with reference to other objects. The article analyses 8 indexes of sustainable development in terms of using biomass for power generation purposes. The analysis was performed to include three social order indices, two economic indices and one environmental order index. It was concluded that the use of biomass in power generation can reduce the emission of greenhouse gasses significantly at several stages: the emission can be eliminated from the biological process of biomass conversion, storage and it can also be reduced during transportation.
Coal combustion processes are the main source of mercury emission to the environment in Poland. Mercury is emitted by both power and heating plants using hard and brown coals as well as in households. With an annual mercury emission in Poland at the level of 10 Mg, the households emit 0.6 Mg. In the paper, studies on the mercury release in the coal and biomass combustion process in household boilers were conducted. The mercury release factors were determined for that purpose. For the analyzed samples the mercury release factors ranged from 98.3 to 99.1% for hard coal and from 99.5% to 99.9% for biomass, respectively. Due to the high values of the determined factors, the amount of mercury released into the environment mainly depends on the mercury content in the combusted fuel. In light of the obtained results, the mercury content in the examined hard coals was 6 times higher than in the biomass (dry basis). Taking the calorific value of fuels into account, the difference in mercury content between coal and biomass decreased, but its content in coal was still 4 times higher. The mercury content determined in that way ranged from 0.7 to 1.7 μg/MJ for hard coal and from 0.1 to 0.5 μg/MJ for biomass, respectively. The main opportunity to decrease the mercury emissions from households is offered by the use of fuels with a mercury content that is as low as possible, as well as by a reduction of fuel consumption. The latter could be obtained by the use of modern boilers as well as by the thermo-modernization of buildings. It is also possible to partially reduce mercury emissions by using dust removal devices.
In the examined area three types of waters have been recorded: Surface Waters of winter modification, Warm Deep Waters and East Bransfield Strait Waters. Geographical location of Scotia Front is similar to that observed in previous years. The dynamics of waters within the examined area is high. It is reflected not only in physical and chemical parameters but also in the distribution of chlorophyll α. In the Front its total amount in a water column is greater than outside.