The organic carbon (OC)-rich, black shale succession of the Middle Triassic Bravaisberget Formation in Spitsbergen contains scattered dolomite-ankerite cement in coarser-grained beds and intervals. This cement shows growth-related compositional trend from non-ferroan dolomite (0–5 mol % FeCO3) through ferroan dolomite (5–10 mol % FeCO3) to ankerite (10–20 mol % FeCO3, up to 1.7 mol % MnCO3) that is manifested by zoned nature of composite carbonate crystals. The d13C (-7.3‰ to -1.8‰ VPDB) and d18O (-9.4‰ to -6.0‰ VPDB) values are typical for burial cements originated from mixed inorganic and organic carbonate sources. The dolomite-ankerite cement formed over a range of diagenetic and burial environments, from early post-sulphidic to early catagenic. It reflects evolution of intraformational, compaction-derived marine fluids that was affected by dissolution of biogenic carbonate, clay mineral and iron oxide transformations, and thermal decomposition of organic carbon (decarboxylation of organic acids, kerogen breakdown). These processes operated during Late Triassic and post-Triassic burial history over a temperature range from approx. 40°C to more than 100°C, and contributed to the final stage of cementation of the primary pore space of siltstone and sandstone beds and intervals in the OC-rich succession.
Diagenetic carbonate deposits (concretions, cementation bodies and cementstone bands) commonly occur in organic carbon-rich sequence of the Agardhfjellet Formation (Upper Jurassic) in Spitsbergen . They are dominated by dolomite/ankerite and siderite. These deposits originated as a result of displacive cementation of host sediment in a range of post-depositional environments, from shallow subsurface to deep-burial ones. Preliminary results of the carbon and oxygen isotopic survey of these deposits in southern Spitsbergen (Lĺgkollane, Ingebrigtsenbukta, Reinodden, and Lidfjellet sections) show the δ13C values ranging between –13.0‰ and –1.8‰ VPDB, and the δ18O values between –16.0‰ and –7.7‰ VPDB. These results suggest that the major stage of formation of the carbonate deposits occurred during burial diagenesis under increased temperature, most probably in late diagenetic to early catagenic environments. Carbonate carbon for mineral precipitation was derived from dissolution of skeletal carbonate and from thermal decomposition of organic matter.
Modern hydrology of a typical Arctic fjord (Hornsund, SW Spitsbergen, Sval− bard) was investigated and compared with commonly used in paleoceanography proxies: benthic foraminiferal assemblages and their stable isotope (#2;18O and #2;13C) composition. The benthic foraminifera from Hornsund comprised 45 species and 28 genera. Their spatial variations follow the zonation pattern, resulting from the influence of Atlantic water at the fjord mouth and glacial meltwaters at the fjord head. At the mouth of the fjord, the total number of species and the contribution of agglutinating species were the highest. In the in− ner part of fjord, the foraminiferal faunas were poor in species and individuals, and aggluti− nating species were absent. “Living” (stained) foraminifera were found to be common throughout the short sediment cores (~10 cm long) studied. The stable isotope values of #2;18O and #2;13C were measured on tests of four species: Elphidium excavatum forma clavata, Cassidulina reniforme, Nonionellina labradorica and Cibicides lobatulus. The results con− firmed the importance of species−specific vital effects, particularly in the case of C. loba− tulus. The variability in the isotopic composition measured on different individuals within a single sample are comparable to isotopic composition of the same species test between sam− pling stations. The temperatures and bottom water salinities calculated from #2;18O values in different foraminifera tests mirrored those recorded for bottom waters in the central and outer fjords relatively well. However, in the case of the inner fjord, where winter−cooled bottom waters were present, the calculated values from #2;18O were systematically higher by about 2#3;C. The obtained results imply that particular caution must be taken in interpretation of fjord benthic foraminifera assemblages in high resolution studies and in selection of ma− terial for isotope analyses and their interpretation in cores from inner fjords or silled fjords, where winter−cooled waters may be present.