Compared to other European countries, Poland has scarce drinking water resources and exhibits significant variation in annual runoff. On the other hand, the geothermal water resources present in sedimentary/structural basins, mostly in the Polish Lowlands and the Podhale geothermal system, not only provide a valuable source of renewable energy, which is utilized, although only to a limited extent, but can also be used for many other purposes. The paper presents the results of studies related to the desalination of low dissolved mineral content geothermal waters from the Bańska IG-1 well using a dual hybrid system based on ultrafiltration and reverse osmosis. The desalination of geothermal waters may be considered a possible solution leading to the decentralization of drinking water supply. In many cases, using cooled waters for drinking purposes may be considered an alternative method of disposing of them, in particular for open drain arrangements, i.e. where cooled water is dumped into surface waters.
M embrane-based water desalination processes and hybrid technologies are often considered as a technologically and economically viable alternative for desalination of geothermal waters. This has been conﬁrmed by the results of pilot studies concerning the UF-RO desalination of geothermal waters extracted from various geological structures in Poland. The assessment of the feasibility of implementing the water desalination process analysed on an industrial scale is largely dependent on the method and possibility of disposing or utilising the concentrate. The analyses conducted in this respect have demonstrated that it is possible to use the solution obtained as a balneological product owing to its elevated metasilicic acid, ﬂuorides and iodides ions content. Due to environmental considerations, injecting the concentrate back into the formation is the preferable solution. The energy efﬁciency and economic analysis conducted demonstrated that the cost effectiveness of implementing the UF-RO process in a geothermal system on an industrial scale largely depends on the factors related to its operation, including without limitation the amount of geothermal water extracted, water salinity, the absorption parameters of the wells used to inject water back into the formation, the scale of problems related to the disposal of cooled water, local demand for drinking and household water, etc. The decrease in the pressure required to inject water into the formation as well as the reduction in the stream of the water injected are among the key cost-effectiveness factors. Ensuring favourable desalinated water sale terms (price/quantity) is also a very important consideration owing to the electrical power required to conduct the UF-RO process.
The article presents the results of studies on the efficacy of water desalination (i.e. Elimination of NaCl ions from the solution) using graphene-polyamide composite membranes. The membrane used for filtration consists of a monolayer of polycrystalline graphene on a porous polyamide carrier support (nylon 66). The degree of desalination for an aqueous NaCl solution percolated through the membrane was 18%. In the future this type of membrane may replace the currently used reverse osmosis membranes.