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Abstract

The process of enrichment in a jig has usually been described and analysed using particle density as a separation feature. However, a degree of particle loosening in the jig bed is affected by, inter alia, the terminal particle free settling velocity which in turn is affected by the size, density and shape of a particle. Therefore, the terminal particle settling velocity clearly characterises the feed transferred to a jig for the enrichment process. Taking the comprehensive particle geometric (particle size and shape) and physical properties (particle density) into account comes down to the calculation of the terminal particle settling velocity. The terminal particle settling velocity is therefore a complex separation feature which comprises three basic particle features (particle density, size and shape). This paper compares the effects of enrichment of coal fines in a jig, for two cases: when the commonly applied particle density is separation feature and for the particle settling velocity. Particle settling velocities were calculated in the selected three particle size fractions: –3.15+2.00, –10.00+8.00 and –20.00+16.00 mm based on the industrial testing of a jig for coal fines and detailed laboratory tests consisting in determining particle density, projective diameter and volume and dynamic particle shape coefficient. The calculated and drawn partition curves for two variants, i.e. when particle density and particle settling velocity were taken into account as the separation argument in selected particle size fractions, allowed to calculate and compare separation precision indicator. With the use of a statistical test, the assumption on the independence of random variables of the distribution of components included in the distribution of the particle settling velocity as a separation feature during enrichment in a jig was verified.
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Abstract

The problem of of the use of fly ash still constitutes a research and exploration area for scientists. This is due to the fact that, 6,000,000 Mg of coal combustion by-products (CCB) are storage on landfills yearly in Poland alone. One of the potential directions of using fly ash is to use it as a substrate in hydrothermal syntheses of mesoporous materials (synthetic zeolites). Zeolites are aluminosilicates with a spatial structure. Due to their specific structure they are characterized by a number of specific properties among others molecular-sieve, ion-exchange and catalytic that can be used in engineering and environmental protection. So far, the synthesis has been carried out using coal combustion by-products such as fly ash or microsphere. The article analyzes whether separation from the fly ash of the appropriate fraction (below 63 μm) will affect the formation of zeolite grains. The syntheses were carried out using class F fly ash and the fraction separated from it, which was obtained by sieving the ash through a 63 μm sieve. Chemical (XRF) and mineralogical (XRD, SEM-EDS) analyzes were carried out for substrates as well as the obtained reaction products. In the case of substrates, the analysis did not show any significant differences between the ash and the separated fraction. However, in products after synthesis (Na-X zeolite with a small amount of Na-P1 zeolite, and small amounts of quartz and unreacted aluminosilicate glass - mullite) higher aluminum and sodium contents were observed from the separated fraction, with a lower calcium and potassium content. A small proportion of illite was observed on the diffraction curve of the zeolite from the fraction. Observations of grain morphology showed no differences in formation. Based on the conducted analyzes, it can be stated that, considering the economics of the synthesis process, the separation of fine fractions from the fly ash does not affect the quality of the synthesis process.
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Abstract

Stability of silver nanoparticles strongly influences the potential of their application. The literature shows wide possibilities of nanoparticles preparation, which has significantly impact on their properties. Therefore, the improvement of AgNPs preparation plays a key role in the case of their practical use. The pH values of the environment are one of the important factors, which directly influences stability of AgNPs. We present a comparing study of the silver nanoparticles prepared by „bottom-up“ methods over by chemical synthesis and biosynthesis using AgNO3 (0.29 mM) solution. For the biosynthesis of the silver nanoparticles, the green freshwater algae Parachlorella kessleri and Citrus limon extracts were used as reducing and stabilizing agents. Chemically synthesized AgNPs were performed using sodium citrate (0.5%) as a capping agent and 0.01% gelatine as a reducing agent. The formation and long term stability of those silver nanoparticles synthesized either biologically and chemically were clearly observed by solution colour changes and confirmed by UV-vis spectroscopy. The pH values of formed nanoparticle solutions were 3 and 5.8 for biosynthesized AgNPs using extract of Citrus limon and Parachlorella kessleri, respectively and 7.2 for chemically prepared AgNPs solution using citrate. The SEM as a surface imaging method was used for the characterization of nanoparticle shapes, size distribution and also for resolving different particle sizes. These micrographs confirmed the presence of dispersed and aggregated AgNPs with various shapes and sizes.
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