In the paper recent progress at VIGO/MUT (Military University of Technology) MOCVD Laboratory in the growth of Hg1-xCdxTe (HgCdTe) multilayer heterostructures on GaAs/CdTe substrates is presented. The optimum conditions for the growth of single layers and complex multilayer heterostructures have been established. One of the crucial stages of HgCdTe epitaxy is CdTe nucleation on GaAs substrate. Successful composite substrates have been obtained with suitable substrate preparation, liner and susceptor treatment, proper control of background fluxes and appropriate nucleation conditions. The other critical stage is the interdi#27;used multilayer process (IMP). The growth of device-quality HgCdTe heterostructures requires complete homogenization of CdTe-HgTe pairs preserving at the same time suitable sharpness of composition and doping profiles. This requires for IMP pairs to be very thin and grown in a short time. Arsenic and iodine have been used for acceptor and donor doping. Suitable growth conditions and post growth anneal is essential for stable and reproducible doping. In situ anneal seems to be sufficient for iodine doping at any required level. In contrast, efficient As doping with near 100% activation requires ex situ anneal at near saturated mercury vapours. As a result we are able to grow multilayer fully doped (100) and (111) heterostructures for various infrared devices including photoconductors, photoelectromagnetic and photovoltaic detectors. The present generation of uncooled long wavelength infrared devices is based on multijunction photovoltaic devices. The technology steps in fabrication of devices are described. It is shown that near-BLIP performance is possible to achieve at ≈ 230 K with optical immersion. These devices are especially promising as 7.89.5 um detectors, indicating the potential for achieving detectivities above 109 cmHz1/2/W.
The study presents the summary of the knowledge of energy-active segments of steel buildings adapted to obtain electrical energy (EE) and thermal energy (TE) from solar radiation, and to transport and store TE. The study shows a general concept of the design of energy-active segments, which are separated from conventional segments in the way that allows the equipment installation and replacement. Exemplary solutions for the design of energy-active segments, optimised with respect to the principle of minimum thermal strain and maximum structural capacity and reliability were given . The following options of the building covers were considered: 1) regular structure, 2) reduced structure, 3) basket structure, 4) structure with a tie, high-pitched to allow snow sliding down the roof to enhance TE and EE obtainment. The essential task described in the study is the optimal adaptation of energy-active segments in large-volume buildings for extraction, transportation and storage of energy from solar radiation.