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Abstract

Osier (salix viminalis) is a promising energy crop for the growing bioenergy purposes in Ukraine. It is unpretentious to the conditions of growth, marked with simplicity of cultivation technology, well-withdrawn for fertilization. Sewage sludge, due to its chemical composition and high content of organic matter, can be successfully used to fertilize the willow. The calculations of bioenergetic and economic efficiency showed that application of sewage sludge and compost with sawdust and straw in a ratio of 3: 1 at osier is marked with a high effect. In the studies performed in conditions of Ukraine’s Precarpathians on sod-podzolic soils we found that the highest biomass output and, therefore, gross energy per unit of area in agrocenoses of osier provided the application of fresh sewage sludge at a rate of 80 t / ha. In this option the dry biomass output made 39.4 t / ha, gross energy with the yield - 1,580 GJ / ha, the costs of energy generation - 6.2 UAH / GJ, the costs of gross output - 17.8 thousand UAH / ha, the rate of energy efficiency - 1.69. However, the highest rates of economic and bioenergetic efficiency after the fourth year of the willow vegetation we observed when the sewage sludge compost with straw of grain crops at a doze 40 and 60 t / ha was applied. In these variants the lowest cost of the biomass production was obtained (at the level 109 - 111 UAH / ton), the cost of the received energy from the biomass (5.6 - 5.7 UAH / GJ), the highest profitability value (97 - 101%) and the best performing of energy efficiency coefficient - 1.85 - 1.89.
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Abstract

The objective of this study was to investigate combustion characteristics of biomass (willow, Salix viminalis) burnt in air and O2/CO2mixtures in a circulating fluidized bed (CFB). Air and oxy-combustion characteristics of wooden biomass in CFB were supplemented by the thermogravimetric and differential thermal analyses (TGA/DTA). The results of conducted CFB and TGA tests show that the composition of the oxidizing atmosphere strongly influences the combustion process of biomass fuels. Replacing N2in the combustion environment by CO2caused slight delay (higher ignition temperature and lower maximum mass loss rate) in the combustion of wooden biomass. The combustion process in O2/CO2mixtures at 30% and 40% O2is faster and shorter than that at lower O2concentrations.
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Abstract

Microporous carbon molecular sieves of extremely narrow pore size distribution were obtained by carbonization of a novel raw material (Salix viminalis). The precursor is inexpensive and widely accessible. The pore capacity and specific surface area are upgradable by H3PO4 treatment without significant change of narrowed PSD. The dominating pore size indicates that these molecular sieves are a potential competitor to other nanoporous materials such as opened and purified carbon nanotubes.
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