The article presents crystallization process of silicon molybdenum ductile cast iron (SiMo). The alloy with 5% silicon content and with variable amounts of Mo in a range of 0-1% was chosen for the research. The carbon content in the analysed alloys did not exceed 3,1%. The studies of crystallization process were based on thermal – derivative analysis (TDA). Chemical composition of all examined samples was analysed with the use of LECO spectrometer. Additionally, the carbon and the sulphur content was determined basing on carbon and sulphur LECO analyser. For metallographic examination, the scanning electron microscopy (SEM) with EDS analyser was used. Disclosed phases have been also tested with the use of X-ray diffraction. The results allowed the description of crystallization processes of silicon molybdenum ductile cast iron using thermal – derivative analysis (TDA). Conducted studies did not allow for the clear identification of all complex phases containing molybdenum, occurring at the grain boundaries. Therefore, the further stages of the research could include the use of a transmission electron microscope to specify the description of complex compounds present in the alloy.
The article presents results of pitting corrosion studies of selected silicon cast irons. The range of studies included low, medium and high silicon cast iron. The amount of alloying addition (Si) in examined cast irons was between 5 to 25 %. Experimental melts of silicon cast irons [1-3] were conducted in Department of Foundry of Silesian University of Technology in Gliwice and pitting corrosion resistance tests were performed in Faculty of Biomedical Engineering in Department of Biomaterials and Medical Devices Engineering of Silesian University of Technology in Zabrze. In tests of corrosion resistance the potentiostat VoltaLab PGP201 was used. Results obtained in those research complement the knowledge about the corrosion resistance of iron alloys with carbon containing Si alloying addition above 17 % [4-6]. Obtained results were supplemented with metallographic examinations using scanning electron microscopy. The analysis of chemical composition for cast irons using Leco spectrometer was done and the content of alloying element (silicon) was also determined using the gravimetric method in the laboratory of the Institute of Welding in Gliwice. The compounds of microstructure were identify by X-ray diffraction.
The article presents results of studies of silicon – molybdenum cast iron (4.42% Si, 2.59% Mo and 2.48% C wt.-%) crystallization process. Metallographic analysis was carried out using SEM-scanning electron microscopy with the EDS system. In order to determine the phase composition, X-ray diffraction studies were performed. Thermo-Calc, a computer simulation program, was used to simulate the crystallization process. . The obtained data allowed to describe the effect of some elements on the crystallization process. The silicon phase of MnSi could not be identified during metallographic studies. Also, computer simulation of the crystallization process did not answer the question at which point the silicon phase of MnSi crystallizes in the tested alloy. Therefore, not all results obtained were linked to the registered crystallization process (TDA process). The EDS analysis revealed an unusual distribution of molybdenum in the microstructure of the sample, where it is clearly visible that the area enriched with this element is also the separation of spheroidal graphite. The possibility of occurrence of Mo-rich micro-areas found in graphite is considered. The case is debatable and difficult to resolve at this stage. Perhaps, at such a high concentration of molybdenum (2.59% Mo) in the alloy, conditions are created for simultaneously crystallization of graphite and molybdenum phases.
Silicon – molybdenum cast iron commonly called SiMo due to its unique properties has becoming more and more interesting engineering material. The history and development of this alloy is relatively long but, due to the significant difficulties during the manufacturing process resulting in the lower final quality than expected, it has not been applied to often in practice. The biggest challenge is its brittleness as a result of the carbides precipitations. During last few years, thanks to the many important researches made and the general foundry technology development, the interest in SiMo iron has been rapidly growing, especially for the castings for heavy duty applications like corrosion, high temperature and wear abrasion resistant parts. In the article the heat treatment attempts to improve the microstructure of SiMo castings has been presented. The goal was to destroy or at least to refine and uniformly distribute the carbides precipitations to improve mechanical properties of the exhaust manifold castings for the cars. The experiments were carried out for the alloy contains approx. 4% Si, 1% Mo and 3.2%C. The range of the research included: hardness measuring, standard mechanical properties and microstructure for as-cast state and after that the subsequent heat treatment process with another properties check. The result of the heat treatment was the elimination of pearlite from the metal matrix. Moreover, the changes of the carbide molybdenum – rich phase morphology were observed. The dispersion of the carbides precipitations in the carbides area was observed. The experiments proved the possibility to control the microstructure and the mechanical properties of the SiMo castings by means of heat treatment but only to some extent.
Ductile irons of the type of Si-Mo are characterized by increased resistance to long-term influence of high temperatures and cyclic temperature changes. They are mainly used in castings of combustion engine exhaust piping and other castings utilized at temperatures of up to 850°C. The aim of the study is to verify the mechanical properties of non-alloyed cast iron EN CSN GJS 450, SiMo4-0.5 and SiMo5-1 ductile irons at temperatures of 700 to 800°C, and the extent of their superficial oxidation after longterm annealing at a temperature of 900°C. Via chemical microanalysis the composition of oxidation products in the surface layer was evaluated.
The results of studies on the use of modern two cored wires injection method for production of ferritic nodular cast iron (ductile iron) with use of unique implementation of drum ladle as a treatment / transport and casting ladle instead vertical treatment ladle was described. The injection of length of Ø 9mm wires, cored: in FeSi + Mg nodulariser mixture and inoculant master alloy is a treatment method which can be used to produce iron melted in coreless induction furnace. This paper describes the results and analysis of using this method for optimal production of ductile iron under specific industrial conditions. It means, that length of nodulariser wire plus treatment and pouring temperatures were optimized. In this case, was taken ductile iron with material designation: EN-GJS-SiMo40-6 Grade according EN 16124:2010 E. Microstructure of great number of trials was controlled on internally used sample which has been correlated with standard sample before. The paper presents typical ferritic metallic matrix and nodular graphite. Additionally, mechanical properties were checked in some experiments. Mean values of magnesium recovery and cost of this new method from optimized process parameters were calculated as well.