The report presents research efforts on the synthesis of Zn/MoS2 composite coatings by electrochemical reduction from a sulphate-borate bath containing MoS2 powder as a dispersion phase at various concentrations. The structure of the Zn/MoS2 composite coatings was characterised and the effect of MoS2 particles embedded on their microhardness was evaluated. The coatings produced are characterized by a compact, homogeneous structure and a good connection to a steel substrate. The incorporation of MoS2 particles into the zinc matrix has an influence on the structure and morphology of the Zn/MoS2 composite coatings. It was found that the presence of MoS2 particles increases surface roughness along with coating hardness. The incorporation of the MoS2 particles into the zinc matrix slightly improves the corrosion resistance compared to Zn coatings, making the corrosion potential shift towards more electropositive values.
An analysis of the effect of drawing speed on the formation of a zinc coating in the multi-stage fine steel wire drawing process has been carried out in the article. Pre-hardened 2.2 mm-diameter material was drawn into 1.00 mm-diameter wire in 6 draws on a multi-stage drawing machine. The drawing process was carried out at a drawing speed of 5, 10, 15, 20 and 20 m/s, respectively. Mechanical tests were tests were performed for the final wires to determine their yield strength, ultimate tensile strength, uniform and total elongation and reduction in area. The thickness of the zinc coating on the wire surface was determined by the gravimetric method and based on metallographic examination. The use of electron scanning microscopy, on the other hand, enabled the identification of individual phases in the zinc coating. The above investigations were supplemented with corrosion testing of 1.00 mm-diameter wires. It has been demonstrated that drawing speed significantly influences not only the thickness of the zinc coating on the drawn wire surface, buts also its morphology and corrosion resistance.
This paper analyses the heat treatment of the hot-dip zinc coating deposited on both cast iron and steel. The aim of research is to increase coating hardness and wear resistance without decreasing its anticorrosion properties. Hot-dip zinc coating was deposited in industrial conditions (acc. PN-EN ISO 10684) on disc shape samples and bolts M12x60. The achieved results were assessed on the basis of microscopic observation (with the use of an optical and scanning microscope), EDS (point and linear) analysis and micro-hardness measurements. It was discovered that the heat treatment of zinc coating results in an increase in hardness which is caused by the corresponding changes in microstructure.
Studies were conducted on a zinc coating produced on the surface of ductile iron grade EN-GJS-500-7 to determine the eutectic grain effect. For this purpose, castings with a wall thickness of 5 to 30 mm were made and the resulting structure was examined. To obtain a homogeneous metal matrix, samples were subjected to a ferritising annealing treatment. To enlarge the reaction surface, the top layer was removed from casting by machining. Then hot dip galvanising treatment was performed at 450°C to capture the kinetics of growth of the zinc coating (in the period from 60 to 600 seconds). Analysing the test results it was found that within the same time of hot dip galvanising, the differences in the resulting zinc coating thickness on samples taken from castings with different wall cross-sections were small but could, particularly for shorter times of treatment, reduce the continuity of the alloyed layer of the zinc coating.
The growth kinetics of the zinc coating formed on the surface of casting made from ductile iron grade EN-GJS-500-3 was investigated. To produce homogenous metal matrix in test samples, the normalising and ferritising annealing was carried out. Studies showed a heterogeneous structure of cast iron with varying content of the phases formed. This was followed by hot dip galvanising treatment at 450°C to capture the growth kinetics of the zinc coating (the time of the treatment ranged from 60 to 600 seconds). Nonlinear estimation of the determined growth kinetics of the alloyed layer of a zinc coating was made and an equation of the zinc coating growth was derived. Based on the results of the investigations it was concluded that thickness of the zinc coating formed on the surface of casting with a 100% pearlitic matrix makes 55% of the thickness of coating formed on the surface in 100% ferritic.