Modern metal forming processes of non-ferrous metals, particularly aluminum and its alloys, are increasingly based on integrated technologies combining numerous operations in one process line. The subject of this paper focuses on the possibility of using materials after mould casting (simulating a continuous casting process between cylindrical crystallizers – Twin Roll Casting method) for the direct cold rolling process. As a part of this research a pilotage study on metallurgical synthesis and mould casting process of Al-Mg alloys with the magnesium contents of 5%-10%, testing their mechanical, electrical and structural properties as well as susceptibility to cold plastic deformation. This process was carried out with the measurement of strength parameters and confirmed the possibility of cold rolling alloys with a casting structure without prior hot deformation.
An overview of the bibliography regarding the connection of knowledge about precious metal alloys and aspects of the use of computer aided technologies to the optimization of the jewelry casting processes is presented. An analysis of the usability of selected CAx systems was made: 1) for spatial design, called Rhinoceros 6 and 2) CAE system: NovaFlow & Solid (NF&S). The authors describe own research including data acquisition and evaluation of temperature variations during solidification of the selected Au-Ag-Cu alloy, with the identification of the phase transformations of this alloy. The intensity of heat exchange was changed (cooling of specimens under ambient temperature conditions – "normal" intensity and with the furnace – very slow cooling). The problem of completing the simulation database was pointed out and analyzed. Examples of simulations of casting selected jewelry (ring and signet) were given and compared with the result of the experiment realized in real conditions. It was confirmed that the optimization by combining experimental and simulation studies allows for the acquisition of new knowledge, and also facilitates the creation of new artistic designs of jewelry as well as performing the feasibility check, and then optimizing the chosen technology.
In order to identify the influence of different Mn, Cd, V and Zr content on the properties of Al-Cu casting alloys in hydraulic valves, orthogonal test methods were used to prepare alloy test bars with different elements and contents. Tensile tests were performed on the test bars so obtained. The microstructure of alloys with different compositions is studied. The results show that adding approximately 0.4% of Mn can not only form a strengthening phase but also reduce the excessive segregation of the matrix along the grain boundary. A Cd content of 0.2% can promote the formation of micro Cd spheres in the softer aluminum matrix. Hard spots increase the wear resistance of the material; however, an excess of Cd will cause element segregation and deteriorate the mechanical properties of the valve body. Zr and V refine the grains in the alloy; however, an excess of these elements will lead to a large area of segregation. If proper heat treatment is lacking, the mechanical properties of the valve body deteriorate.
The main goal of the presented work was to determine the relationship between changes in the shape of the derivative curve and the microstructure of Zn-Al-Cu alloys before and after modification. To describe the phenomena that occur in the material during solidification as a result of the modification in the chemical composition, the thermal-derivative analysis method was applied. This method allows to describe and interpret the kinetics of crystallisation of the tested alloys. To describe the morphology and phase composition, light and electron microscopy (SEM, TEM) was also used. The modification of the hypereutectic Zn-Al-Cu alloys with the addition of Ce causes a reduction in the size α' + η eutectics and change in the morphology of the α' phase precipitates from dendritic to “tweed”.
The casting workshop was discovered with numerous artifacts, confirming the existence of the manufacturing process of metal ornaments using ceramic molds and investment casting technology in Lower Silesia (Poland) in 7-6 BC. The research has yielded significant technological information about the bronze casting field, especially the alloys that were used and the artifacts that were made from them. Based on the analyses, the model alloys were experimentally reconstructed. Taking advantage of the computer-modeling method, a geometric visualization of the bronze bracelets was performed; subsequently, we simulated pouring liquid metal in the ceramic molds and observed the alloy solidification. These steps made it possible to better understand the casting processes from the perspective of the mold technology as well as the melting and casting of alloys.
Experimental Mg-Al-RE type magnesium alloys for high-pressure die-casting are presented. Alloys based on the commercial AM50 magnesium alloy with 1, 3 and 5 mass % of rare earth elements were fabricated in a foundry and cast in cold chamber die-casting machines. The obtained experimental casts have good quality surfaces and microstructure consisting of an α(Mg)-phase, Al11RE3, Al10RE2Mn7 intermetallic compound and small amount of α+γ eutectic and Al2RE phases.
This paper considers the assessment of attenuation in aluminium alloys castings and in cast iron prepared by gravity casting method and by casting under pressure. The issue of ultrasound attenuation is important in setting the conditions of non-destructive (NDT) testing, especially in casted materials. The characteristics of the ultrasonic technique and ultrasonic attenuation and the calculation of the attenuation and the velocity of ultrasound are presented in the theoretical part of this paper. For experimental measurements, cylindrical castings from AlSi alloy (a hypoeutectic alloy with a silicon content of about 7% - AlSi7 and a eutectic alloy with a silicon content of about 12% - AlSi12) and from grey and ductile cast iron were made. The ultrasonic records of the casting control, the calculation of ultrasound attenuation for individual samples are listed and described in the experimental part. The evaluation of measurements and comparison of calculated ultrasound attenuation is at the end of this article.
The chosen, typical causes of quality defects of cast-iron „alphin” rings embedded in aluminum cast are being presented in this paper. Diffusive joint of those inserts with the pistons casts is being used, due to extreme work conditions of destructive influence of the fuel mix and variable thermo-mechanical loads, which reign in the combustion motor working chamber.
The paper present the examination results concerning mechanical properties of castings made of AlSi7MG alloy in correlation both with the most significant squeeze casting parameters and with the modification treatment. Experiments were planned and held according to the 2 3 factorial design. The regression equations describing the influence of the squeeze pressure, the mould temperature, and the quantity of strontium modifier on the strength and elongation of the examined alloy were obtained. It was found that the main factor controlling the strength increase is the squeeze pressure, while the plasticity (A5 ) of the alloy is affected most advantageously by modification. The application of modification treatment in squeeze casting technology enables for production of the slab-type castings made of AlSi7Mg alloy exhibiting strength at the level of 230 MPa and elongation exceeding 14%.
The work presents the results of the studies of Co-Cr-Mo casting alloys used in the production of frame casts of removable dentures, crowns and bridges in dental prosthetics. The studies were performed on four Co-Cr-Mo alloys of different contents of Mo, W and other additives. Electrochemical tests were performed, which aimed at examining the corrosion resistance of the alloys and observing the alloy structure after chronoamperometric tests with the potential in the area of the occurrence of the passive layer breakpoint. The alloy microstructure images after chronoamperometric tests show the presence of non-uniformly distributed general corrosion. Moreover, a project of cobalt alloy casting was elaborated using a ceramic mold casting. Additionally, analysis of the obtained microstructure was performed. The microstructure of the examined alloys was of the dendrite type. This microstructure was chemically inhomogeneous and consisted of an austenitic matrix formed by a solid cobalt solution and chromium in the core dendritic structure.
Magnesium alloys are one of the lightest of all the structural materials. Because of their excellent physical and mechanical properties the alloys have been used more and more often in various branches of industry. They are cast mainly (over 90%) on cold and hot chamber die casting machines. One of the byproducts of casting processes is process scrap which amounts to about 40 to 60% of the total weight of a casting. The process scrap incorporates all the elements of gating systems and fault castings. Proper management of the process scrap is one of the necessities in term of economic and environmental aspects. Most foundries use the process scrap, which involves adding it to a melting furnace, in a haphazard way, without any control of its content in the melt. It can lead to many disadvantageous effects, e.g. the formation of a hard buildup at the bottom of the crucible, which in time makes casting impossible due to the loss of the alloy rheological properties. The research was undertaken to determine the effect of an addition of the process scrap on the mechanical properties of AZ91 and AM50 alloys. It has been ascertained that the addition of a specific amount of process scrap to the melt increases the mechanical properties of the elements cast from AZ91 and AM50 alloys. The increase in the mechanical properties is caused mainly by compounds which can work as nuclei of crystallization and are introduced into the scrap from lubricants and anti-adhesive agents. Furthermore carbon, which was detected in the process scrap by means of SEM examination, is a potent grain modifier in Mg alloys [1-3]. The optimal addition of the process scrap to the melt was determined based on the statistical analysis of the results of studies of the effect of different process scrap additions on the mean grain size and mechanical properties of the cast parts.
The formation of oxide film on the surface of aluminium melts, i.e. bifilms, are known to be detrimental when they are incorporated into the cast part. These defects causes premature fractures under stress, or aid porosity formation. In this work, Al-12 Si alloy was used to cast a step mould under two conditions: as-received and degassed. In addition, 10 ppi filters were used in the mould in order to prevent bifilm intrusion into the cast part. Reduced pressure test samples were collected for bifilm index measurements. Samples were machined into standard bars for tensile testing. It was found that there was a good agreement with the bifilm index and mechanical properties.
This paper discusses the joining of AZ91 magnesium alloy with AlSi17 aluminium alloy by compound casting. Molten AZ91 was cast at 650oC onto a solid AlSi17 insert placed in a steel mould under normal atmospheric conditions. Before casting, the mould with the insert inside was heated up to about 370oC. The bonding zone forming between the two alloys because of diffusion had a multiphase structure and a thickness of about 200 µm. The microstructure and composition of the bonding zone were analysed using optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. The results indicate that the bonding zone adjacent to the AlSi17 alloy was composed of an Al3Mg2 intermetallic phase with not fully consumed primary Si particles, surrounded by a rim of an Mg2Si intermetallic phase and fine Mg2Si particles. The bonding zone near the AZ91 alloy was composed of a eutectic (an Mg17Al12 intermetallic phase and a solid solution of Al and Si in Mg). It was also found that the compound casting process slightly affected the AZ91alloy microstructure; a thin layer adjacent to the bonding zone of the alloy was enriched with aluminium.
The results of castability and structures researches of two nickel base alloys - Ceranium CN and Magnum AN applied on casting of the crowns and dental bridges are presented. Studies were carried out on the alloys cast under the centrifugal force to the moulds made by the lost wax method using production line of ROKO. Having regard to a specific technology of casting and possibility of ROKO production line, to the estimation of alloys castability a spiral test was adjusted with a 0,8 mm and a 2,5 mm diameter of test casting. Measuriements executed on a 20 test castings allowed to establish, that castability of Magnum AN alloy was 65 % greater than castability of Ceranium NC alloy. The results of thermodynamics calculations of the equilibrium and nonequilibrium crystallization (Scheil model) of the investigated alloys are presented too. The characteristic temperatures of phase transformation and forecast phase composition of alloys for both kind of crystallization were calculated. It is established after structural supervisions, that the investigated alloys crystallize in dendryte form and in centrifugal casting conditions have cooling rate sensivity and inclination to texture structure forming in outmost layer of casting. Phase composition of alloys corresponds to the results of thermodynamics calculations of the nonequilibrium crystallization conditions.
Investment casting technology that utilizes lost-wax casting is one of the most-important achievements of ancient society. In Lower Silesia, Poland (Grzybiany, Legnica county), a 7-6 BC casting workshop was discovered with numerous artifacts, confirming the existence of the manufacturing process of metal ornaments using ceramic molds. The paper presents the research of molds and casts from the Bronze and Early Iron Ages. Microscopic analyses of the casting molds were performed, along with radiographic and chemical composition tests of the artifacts (the latter employing the use of the X-ray fluorescence spectroscopy method). The clustering method was used for alloy classification. The microstructure was analyzed by means of Scanning Electron Microscopy with Energy Dispersive Spectroscopy. Conclusions from the research were utilized in further experiments
The work presents the test result of the influence of cooling rate on the microstructure of AZ91 alloy, Vickers micro-hardness and Brinell hardness. Studies cooling and crystallization of AZ91 alloy was cast into the ceramic shells pre-heated to 180 ° C and then air-cooled at ambient temperature or intensively super cooled in the liquid coolant. The TDA method was applied to record and characterize the thermal effect resulting from the phase transformations occurring during the crystallization of AZ91 alloy. The kinetics and dynamics of the thermal processes of crystallization of AZ91 alloy in the ceramic shells were determined. Metallographic tests were performed with the use of an optical microscope. A comparison of these test results with the thermal effect recorded by way of the TDA method was made. Influence of cooling rate of AZ91 on HV0, 01 micro-hardness and Brinell hardness alloy was examined.
The study presents the results of the investigations of the effect of Cu, Ni, Cr, V, Mo and W alloy additions on the microstructure and mechanical properties of the AlSi7Mg0.3 alloy. The examinations were performed within a project the aim of which is to elaborate an experimental and industrial technology of producing elements of machines and devices complex in their construction, made of aluminium alloys by the method of precision investment casting. It was demonstrated that a proper combination of alloy additions causes the crystallization of complex intermetallic phases in the silumin, shortens the SDAS and improves the strength properties: Rm, Rp0.2,HB hardness. Elevating these properties reduces At, which, in consequence, lowers the quality index Q of the alloy of the obtained casts. Experimental casts were made in ceramic moulds preliminarily heated to 160 °C, into which the AlSi7Mg0.3 alloy with the additions was cast, followed by its cooling at ambient temperature. With the purpose of increasing the value of the quality index Q, it is recommended that the process of alloy cooling in the ceramic mould be intensified and/or a thermal treatment of the casts be performed (ageing)(T6).
The results of estimation of home scrap addition in charge influence on durability and wear of casting instrumentation life in the highpressure casting technology using the hot chamber machine of alloy of AZ91 are presented. The wear of the following elements of the casting instrumentation so-called "casting set" as: syphon, plunger, sliding-rings, nozzle and injection moulding nozzle was estimated. A wear was estimated quantitative by registering the number of mould injections for different charges to the moment of element damage supervision. A damage had to be at such level that liquidated an element from further exploitation and necessary was an exchange on new or regeneration. In a final result allowed it the detailed determination of durability of the applied rigging elements in dependence on the type of the applied type of melt. It is noticed, that together with the increase of home-scrap participation in the charge wear of pressure machine instrumentation elements increases.
Fatigue investigations of two 4XXX0-series aluminum alloys (acc. PN-EN 1706) within a range of fewer than 104 cycles at a coefficient of cycle asymmetry of R = –1 were performed in the current paper. The so-called modified low-cycle test, which provided additional information concerning the fatigue life and strength of the tested alloys, was also performed. The obtained results were presented in the form of diagrams: stress amplitude σa – number of cycles before damage N. On the basis of the microscopic images of sample fractures, the influence of the observed casting defects on the decrease of cycle numbers at a given level of stress amplitude were analyzed. Based on the images and dimensions of the observed defects, stress intensity factor KI was analytically determined for each. Their numerical models were also made, and stress intensity factor KI was calculated by the finite element method (FEM).
The work presents the results of the investigations of the effect of inhibitors coated on the internal walls of a ceramic mould on the quality of the obtained casts made of the AM60 alloy containing additions of chromium and vanadium. In order to reduce the reactivity of magnesium alloy cast by the technology of investment casting with the material of the mould and the ambient atmosphere, solid inhibitors were applied in the form of a mixture of KBF4 and H3BO3 after the stage of mould baking and before the mould’s being filled with the liquid alloy. For the purpose of examining the effect of the inhibitors on the surface quality of the obtained casts, profilometric tests were performed and the basic parameters describing the surface roughness, Ra, Rz and Rm, were determined.
Nowadays, the most popular production method for manufacturing high quality casts of aluminium alloys is the hot and cold chamber die casting. Die casts made of hypereutectoid silumin Silafont 36 AlSi9Mg are used for construction elements in the automotive industry. The influence of the metal input and circulating scrap proportion on porosity and mechanical properties of the cast has been examined and the results have been shown in this article. A little porosity in samples has not influenced the details strength and the addition of the circulating scrap has contributed to the growth of the maximum tensile force. Introducing 80% of the circulating scrap has caused great porosity which led to reduce the strength of the detail. The proportion of 40% of the metal input and 60% of the circulating scrap is a configuration safe for the details quality in terms of porosity and mechanical strength.
The study presents the results of the application of a statistical analysis for the evaluation of the effect of high-melting additions introduced into a pressure cast Al-Si alloy on the obtained level of its proof stress Rp0.2. The base Al-Si alloy used for the tests was a typical alloy used for pressure casting grade EN AC-46000. The base alloy was enriched with high-melting additions, such as: Cr, Mo, V and W. The additions were introduced into the base Al-Si alloy in all the possible combinations. The content of the particular high-melting addition in the Al-Si alloy was within the scope of 0.05 to 0.50%. The investigations were performed on both the base alloy and alloy with the high-melting element additions. Within the implementation of the studies, the values of Rp0.2 were determined for all the considered chemical compositions of the Al-Si alloy. A database was created for the statistical analysis, containing the independent variables (chemical composition data) and dependent variables (examined Rp0.2 values). The performed statistical analysis aimed at determining whether the examined high-melting additions had a significant effect on the level of Rp0.2 of the Al-Si alloy as well as optimizing their contents in order to obtain the highest values of the Al-Si alloy's proof stress Rp0.2. The analyses showed that each considered high-melting addition introduced into the Al-Si alloy in a proper amount can cause an increase of the proof stress Rp0.2 of the alloy, and the optimal content of each examined high-melting addition in respect of the highest obtained value of Rp0.2 equals 0.05%.
The paper presents tribological properties of A390.0 (AlSi17Cu5Mg) alloy coupled in abrasive action with EN-GJL-350 grey cast-iron. The silumin was prepared with the use of two different technologies which differed in terms of cooling speed. In the first case the alloy was modified with foundry alloy CuP10 and cast to a standard tester ATD and in case of second option the modified alloy was cast into steel casting die. Due to different speed of heat removal the silumins varied in structure, particularly with size of primary crystals of silicon and their distribution in matrix which had a significant influence of friction coefficient in conditions of dry friction.
The paper presents the results of investigations concerning the influence of negative (relative) pressure in the die cavity of high pressure die casting machine on the porosity of castings made of AlSi9Cu3 alloy. Examinations were carried out for the VertaCast cold chamber vertical pressure die casting machine equipped with a vacuum system. Experiments were performed for three values of the applied gauge pressure: -0.3 bar, -0.5 bar, and -0.7 bar, at constant values of other technological parameters, selected during the formerly carried initial experiments. Porosity of castings was assessed on the basis of microstructure observation and the density measurements performed by the method of hydrostatic weighing. The performed investigation allowed to find out that – for the examined pressure range – the porosity of castings decreases linearly with an increase in the absolute value of negative pressure applied to the die cavity. The negative pressure value of -0.7 bar allows to produce castings exhibiting porosity value less than 1%. Large blowholes arisen probably by occlusion of gaseous phase during the injection of metal into the die cavity, were found in castings produced at the negative pressure value of -0.3 bar. These blowholes are placed mostly in regions of local thermal centres and often accompanied by the discontinuities in the form of interdendritic shrinkage micro-porosity. It was concluded that the high quality AlSi9Cu3 alloy castings able to work in elevated temperatures can be achieved for the absolute value of the negative pressure applied to the die cavity greater than 0.5 bar at the applied set of other parameters of pressure die casting machine work.
The article presents chosen aspects of foundry engineering of the settlement dwellers, including the archaeometric characteristics and metal science analysis of the artefacts, as well as an attempted reconstruction of the production organization. Discovered in Szczepidło (Greater Poland), the foundry workshop is unique in Central European Bronze Age. This workshop foundry operated roughly XIV-XII Century BC. Its production is evidenced by the presence of markers of the whole production cycle: semi-finished and finished products, production waste, fragments of crucibles and casting ladles with traces of usage, and tools. On this basis, the alloys and foundry technologies used have been described. The analysis of foundry technology of copper alloys in the settlement area was carried out by observing the surface and structure of the products, semi-finished artefacts and fragments of crucibles by applying optical microscopy (OM), confocal microscopy (CLSM) and Xray radiography (RT). The investigations of compositions were made by means of the energy dispersive X-ray fluorescence spectroscopy (ED-XRF) and scanning electron microscopy (SEM) coupled with an energy dispersive X-ray analysis system (EDS).