The paper analyses the as-cast state structure of chromium cast iron designed for operation under harsh impact-abrasive conditions. In the process of chromium iron castings manufacture, very strong influence on the structure of this material have the parameters of the technological process. Among others, adding to the Fe-Cr-C alloy the alloying elements like tungsten and titanium leads to the formation of additional carbides in the structure of this cast iron, which may favourably affect the casting properties, including the resistance to abrasive wear.
To investigate the adsorptive properties of a local laterite deposited in Chenzhou, Hunan province, China, the adsorptive properties of the natural laterite were investigated by batch technique in this study. The effects of contact time, pH, ionic strength, temperature, and the concentration on adsorption properties were also analyzed. The obtained experimental results show that the main mineral composition of laterite is kaolinite and montmorillonite. The adsorption process achieved equilibrium within 60 minutes and 90 minutes for Sr(II) and Cr(VI), respectively. The adsorption capacities for Cr(VI) and Sr(II) by the laterite were about 7.25 mg·g-1 and 8.35 mg·g-1 under the given experimental conditions, respectively. The equilibrium adsorption data were ﬁtted to the second-order kinetic equation. The adsorption capacity for Sr(II) onto the laterite increased with increasing pH from 3–11 but decreased with increasing ionic strength from 0.001 to 1.0 M NaCl. The Sr(II) adsorption reaction on laterite was endothermic and the process of adsorption was favored at high temperature. Similarly, the adsorption capacity for Cr(VI) onto the laterite increased with increasing pH from 3–11, however, the ionic strength and temperature had an insigniﬁcant effect on Cr(VI) adsorption. The adsorption of Cr(VI) and Sr(II) was dominated by ion exchange and surface complexation in this work. Furthermore, the Langmuir and Freundlich adsorption isotherm model was used for the description of the adsorption process. The results suggest that the studied laterite samples can be effectively used for the treatment of contaminated wastewaters.
The purpose of the study was to optimize the removal of Cr(VI) by means of the Trichoderma viride strain isolated from chromium mud samples a well as the Aspergillus niger and Penicillium citrinum strains from other environments. The growth of organism and removal of chromium(VI) was carried out in water solution of various chromium(VI) contents. The research was carried out at optimal pH for each fungus i.e. Aspergillus niger 4.0, Penicillium citrinum 5.0 and Trichoderma viride 4.5. During 14 days of incubation, samples of 5 ml each were collected every day in order to determine chromium(VI) content in the solution and the efficiency of bioaccumulation of this element was then specified. Furthermore, chromium contents in filtrate and mycelium were checked to verify this type of biological activity of microorganisms. The fungi culture investigated in this study could grow at 10-125 mg/l chromium concentration which indicated that it was characterized by high tolerance to various concentrations of chromium. At 125 mg/l chromium, these organisms could accumulate successfully about 90% of chromium. High tolerance of this culture can make it a potential candidate to be a heavy metal scavenger of chromium.
The present paper is a presentation of results of a study on morphology, chemical composition, material properties (HVIT, HIT, EIT), and nanoindentation elastic and plastic work for carbide precipitates in chromium cast iron containing 24% Cr. It has been found that the carbides differ in chemical composition, as well as in morphology and values characterizing their material properties. The carbides containing the most chromium which had the shape of thick and long needles were characterized with highest values of the analyzed material properties.
The paper concerns the processes connected with the formation of chromium white cast iron microstructure. The influence of titanium and strontium on the alloy crystallization has been described using TDA method and EDS analysis. Conducted experiments allowed the determination of the selected additions influence on the microstructure of examined alloys. TDA analysis enabled indication of the characteristic temperatures of thermal effects for samples with strontium and titanium and the comparison of results for the reference sample without additions. The results of TDA test also included the analysis of the temperature first derivative values, which presented interesting differences as well. The scanning microscopy observation clearly indicated the difference between the effect of strontium and titanium on the alloy microstructure. The EDS analysis helped to identify the chemical composition of the evolving phases and confirmed the strontium presence in the eutectic. Experimental results allowed to draw reliable conclusions about the effect of applied additions on the crystallization and microstructure of chromium cast iron.
The results of research on stereological parameters of carbides in modified hypoeutectic chromium cast iron were shown in the paper. The effect of distance the casting heat centre of casting to the carbide phase morphology was examined. The samples for metallographic examination were taken from various locations of the model casting prepared in a special tester. This model casting was designed to simulate the solidification of heavy castings. Using the proposed methodology the relation of the distance from the model mould and the size, perimeter, length, width and the shape factor of carbides was examined. During the analysis, the values of stereological parameters of carbides changed on various sections of the model casting.
Laboratory and field experiments have been conducted to study mobility of chromium and lead in floodplain sediments. The main goal of the research was to verify a hypothesis whether changes of chromium and lead concentration could be used to estimate the relative age of floodplain deposits. The basis for undertaking such research was the presence of weaving industry centers in the Obra River valley between the 16th and the 19th century and using Cr and Pb compounds in paint recipes. The Cr and Pb contents were also analyzed in three vertical profiles unaffected by the field experiments. The age of organic sediments in each of the profiles was determined using the radiocarbon analysis. The results of the laboratory experiments have shown that the highest contents of the elements were noted in the surface layer of the sediments placed in the column. However, the contents decreased during the last phase of the experiments and both vertical and horizontal migration of both elements was observed. A more intensive mobility was observed in the field test. Its cause could be the changes of the groundwater level, floodplain inundation and pH conditions in alluvial deposits. Such processes may have influenced migration of the compounds originating from the weaving industry production; Cr and Pb contents detected in the profiles unaffected by the field experiment were too small to be used for relative dating of alluvial deposits. Moreover, the alluvial deposits with increased contents of the studied elements may be older than the period of the weaving industry development. Cr and Pb mobility was especially intensive in the profiles situated within the near bed zone of the floodplain due to regular inundation, and the activity of erosion and accumulation processes entraining the studied elements back to transport in the river bed.
The paper deals with hypereutectic high chromium cast irons. The subject of examination was the effect of various alloying elements (Ti, W, Mo, V) on the size of primary carbides and on the resultant material hardness. Using a scanning electron microscope with a wave dispersion analyser, the carbon content in carbides was established. To determine the other elements, an energy dispersion analyser was used. It was found that both the primary and the eutectic carbides were of the M7C3 type and very similar in composition. The carbides always contained Cr and Fe, and also W, Mo, V or Ti, in dependence on the alloying elements used. The structure of materials containing only chromium without any alloying additions exhibited coarse acicular primary carbides. The structure of materials alloyed with another element was always finer. Marked refinement was obtained by Ti alloying.
The present investigation focuses on the study of the influence of titanium inoculation on tribological properties of High Chromium Cast Iron. Studies of tribological properties of High Chromium Cast Iron, in particularly the wear resistance are important because of the special application of this material. High Chromium Cast Iron is widely used for parts that require high wear resistance for example the slurry pumps, brick dies, several pieces of mine drilling equipment, rock machining equipment, and similar ones. Presented research described the effects of various amounts of Fe-Ti as an inoculant for wear resistance. The results of wear resistance were collated with microstructural analysis. The melts were conducted in industrial conditions. The inoculation was carried out on the stream of liquid metal. The following amount of inoculants have been used; 0.17% Fe-Ti, 0.33% Fe-Ti and 0.66% Fe-Ti. The tests were performed on the machine type MAN. The assessment of wear resistance was made on the basis of the weight loss. The experimental results indicate that inoculation improve the wear resistance. In every sample after inoculation the wear resistance was at least 20% higher than the reference sample. The best result, thus the smallest wear loss was achieved for inoculation by 0.66% Fe-Ti. There is the correlation between the changing in microstructure and wear resistance. With greater amount of titanium the microstructure is finer. More fine carbides do not crumbling so quickly from the matrix, improving the wear resistance.
The article presents results of heat treatment on the high chromium cast iron. The study was carrying out on samples cut from the casting made from chromium cast iron. Those were hardened at different temperatures, then tempered and soft annealed. The heat treatment was performed in a laboratory chamber furnace in the Department of Engineering Alloys and Composites at Faculty of Foundry Engineering AGH. At each stage of the heat treatment the hardness was measured by Vickers and Rockwell methods, and the microscope images were done. Additionally based on images from the optical microscope the microstructure was assessed. Based on these results, the effect of hardening, tempering and soft annealing on the microstructure and hardness of high chromium cast iron was studied. Next the effects of different hardening temperatures on the properties of high chromium cast iron were compared. The study led to systemize the literature data of the parameters of heat treatment of high chromium cast iron, and optimal conditions for heat treatment was proposed for casts of similar properties and parameters.
Results of investigations of wear resistant of two species of cast steel were introduced in the article (low-alloyed and chromium cast steel) on the background of the standard material which was low alloy wear resistant steel about the trade name CREUSABRO ®8000. The investigations were executed with two methods: abrasive wears in the stream of loose particles (the stream of quartz sand) and abrasive wears particles fixed (abrasive paper with the silicon carbide). Comparing the results of investigations in the experiments was based about the counted wear index which characterizes the wears of the studied material in the relation to the standard material.
The present work, presented the study of effect of different inoculants on impact toughness in High Chromium Cast Iron. The molds were pouring in industrial conditions and samples were tested in laboratory in Faculty of Foundry Engineering at AGH. Seven samples were tested - one reference sample, three with different addition of Fe-Ti, and three with different addition of Al. The samples were subjected to impact toughness on Charpy hammer and the hardness test. The presented investigations indicate that for the each inoculant there is an optimal addition at which the sample obtained the highest value of impact toughness. For the Fe-Ti it is 0.66% and for Al is 0.17%. Of all the examined inoculants best results were obtained at a dose of 0.66% Fe-Ti. Titanium is a well-known as a good modifier but very interesting results gives the aluminum. Comparing the results obtained for the Fe-Ti and Al can be seen that in the case of aluminum hardness is more stable. The hardness of all samples is around 40-45 HRC, which is not high for this type of cast iron. Therefore, in future studies it is planned to carry out the heat treatment procedure that may improves hardness.
The article shows results of studies of primary crystallization and wear resistance of Cr-Ni-Mo cast steel intended for work in corrosive and abrasive conditions. The studies of primary crystallization were conducted with use of TDA method and modified tester allowing measurement casting cooling time influence on the cooling and crystallization curves of studied alloys. After heat treatment of examined cast steel wear tests of the samples were conducted on pin-on-disc type device.
Paper presents the results of studies on primary crystallization and wear resistance of high chromium cast iron inoculated with ferrotitanium intended for work in abrasive conditions. Primary crystallization was examined with use of TDA method, wear tests of the samples were conducted using the modified pin-on-disk method.
The paper presents results of Ti-addition to High Chromium Cast Iron (HCCI) on the structure and selected mechanical properties. For this study casted two sets of cylinders with dimensions ø20 mm, ø15 mm x 250 mm, for the High Chromium Cast Iron (HCCI) and with the 4% by mass Ti-addition. Melts were performed in the induction furnace crucible capacity of 15 kg. During the heats the cup with installed S type thermocouple was poured to record the cooling curves. The cylinders were subjected to the static bending strength test. Samples for the test microstructure and Rockwell hardness were cut from the cylinders. The study shows that the addition of titanium had an impact on the structure and thus the properties of High Chromium Cast Iron (HCCI). In subsequent studies, through an appropriate choice of chemical composition and proper process control, it is planned to obtain in the structure the titanium carbides TiC and chromium carbides with type (Cr, Fe)7C3.
The paper presents results of the possibility of adapting the Althoff-Radtke test for High Chromium Cast Iron. The Althoff-Radtke test is a clump attempt used for steel. The Althoff-Radtke test has four different lengths of clamp which qualifies it as a test to quantitatively take into account different kinds of shrinkage ΔL. The length of the slot of the cracked corner and the length of each staple (50 - 350 mm) are the parameters tendency to cast cracks. Castings of white cast iron have a high tendency to hot cracking due to the large range of solidification temperatures, unfavorable kinetics parameters of shrinkage, and especially a lack of expansion before shrinkage. Shrinkage of high chromium white cast iron is similar to the shrinkage of cast steel, and is approximately 2%. Therefore it is important to test susceptibility to hot cracks. Research was carried out under industrial conditions. Four melts were performed, one of the initial chemical composition and the other three modified by different amounts of Fe-Ti, respectively, 0.25%, 0.5% and 0.75% Fe-Ti. The propensity for hot cracking was based on the observation of the dark surface in the corner of the sample. The study shows that the Althoff-Radtke test can be adapted to determine the tendency for hot cracking of high chromium cast iron. It should however be noted that the test results cannot be compared with those for other alloys.
In the paper the results and analysis of abrasive wear studies were shown for two grades of cast steels: low-alloyed cast steel applied for heavy machinery parts such as housing, covers etc. and chromium cast steels applied for kinetic nodes of pin-sleeve type. Studies were performed using the modified in Department of Foundry pin-on-disc method.
The paper presents the results of studies on the development of manufacturing technologies to cast hearth plates operating in chamber furnaces for heat treatment. Castings made from the heat-resistant G-X40CrNiSi27-4 steel were poured in hand-made green sand molds. The following operations were performed: computer simulation to predict the distribution of internal defects in castings produced by the above mentioned technology with risers bare and coated with exothermic and insulating sleeves, analysis of each variant of the technology, and manufacture of experimental castings. As a result of the conducted studies and analysis it was found that the use of risers with exothermic sleeves does not affect to a significant degree the quality of the produced castings of hearth plates, but it significantly improves the metal yield.
High-chromium cast irons are used as abrasion resistant materials. Their wear resistance depends on quantity of carbides and the matrix supporting these carbides. The paper presents the results of cast irons of chemical composition (in wt. %) 19–22 Cr and 2–4.5 C alloyed by 1.7 Mo + 5 Ni + 2 Mn to improve their toughness, which were tested in working conditions of ferroalloys crushing. Tests showed that these as-cast chromium cast irons with mostly austenitic matrix achieved the hardness of 38-45 HRC, but their relative abrasion resistance Ψ ranged from 1.3 to 4.6, was higher comparing to the tool made from the X210Cr12 steel heat treated on hardness 61 HRC. The transformation of austenite into martensite occurs not only at the worn strained areas (on a surface of scratch) but also in their neighbourhood. Due to the work hardening of relatively large volumes of transformed austenite the cast iron possesses high abrasion resistance also on the surfaces where low pressures are acting. The tough abrasion-resistant cast iron well proved for production of dynamic and wear stressed castings e.g., crusher hammers, cutting tools for ceramic etc.