Petrographic and physico-chemical analyses of ashes are carried out on a large scale and presented in numerous scientific papers. The mentioned ashes are obtained from filters and electrostatic precipitators mounted in large industrial installations. The large-scale analysis of the ashes obtained directly from grate furnaces or blast furnaces mounted in low-power boilers started with combating smog and low-stack emissions. The collection of ash samples from household furnaces usually involves the analysis of the combustion of waste in low-power boilers. This is justified in the case of old type boilers, which were designed to use virtually any fuel. Currently, new types of boilers, designed to burn dedicated fuels, are offered on the market. The aim is to use only renewable fuels (biomass) or fossil fuels with high quality parameters, which are more environment-friendly, e.g. eco-pea coal, lignite briquettes, or peat briquettes. The authors of the study focused on examining the ash obtained from boilers for burning wood pellets by performing microscopic analysis of residues after biomass combustion. The above mentioned analysis provides a comprehensive information on the efficiency of the combustion process, the content of contaminants remaining in the ash, and the suitability of ash for other applications. The entire process, from the moment of collecting the samples to the execution of the analysis takes up to 12 hours, which ensures a quick decision on furnace adjustment or fuel change. The ash components were determined based on the results obtained by the Fly-Ash Working Group of the International Committee for Coal and Organic Petrology (ICCP). The mentioned classification has been supplemented with new key elements occurring in ashes resulting from the combustion of wood pellets in household boilers. This allowed determining the percentage content of characteristic components in the tested material, which can be used as a specific benchmark when issuing opinions on the quality and efficiency of the boiler and the combusted pellets.
Wood pellets are classified as a solid biomass type. They are one of the most popular bio-heating fuels used in Europe, especially in the small heating sector, where pellets are burned in low-power domestic boilers. The pellets and automatic pellet-fired heating devices gained popularity due to the increasing air pollution (smog) problem and the low emission limiting campaigns associated with it. Wood pellets are formed as a result of small forestry particles mechanical compression (mainly conifers originated) and they are listed among renewable energy sources. The purpose of the presented studies was to compare the quality of wood pellets used for pellet-fired boilers and to identify, qualitatively and quantitatively, impurities marked in the samples obtained from the domestic market. The application of petrographic analyses, applied so far in relation to fossil fuels, is a presented work innovation for wood pellets. The microscopic analyses were performed on both certified (ENplus/DINplus) and uncertified wood pellets available on the market. Unfortunately, the analysis revealed that the quality requirements were not met, because of the unacceptable contamination presence. The unacceptable organic inclusions in the analyzed samples are fossil coals and their derivatives, coke, and polymeric materials of natural origin. Unacceptable inorganic inclusions determined in the analyzed samples were: glass, slag, rust, pieces of metal, stone powder, plastic, and polymeric materials of inorganic origin.
Natural gas combustion was carried out in air enriched with oxygen in the amount of 25 and 29% with addition of CO2 in place of part of nitrogen. The research was carried out at different flow rates of gas and oxygen excess ratios. The concentration of CO and NOx was analyzed. It has not been proved that the increased oxygen concentration influences significantly the CO concentration. However, the addition of CO2 caused a substantial variability of CO concentration in the exhaust gas, in contrast to the concentration of NOx which decreased monotonically. Model calculations, performed with use of FactSage, indicate an increase in the concentration of CO not only for the air enriched with oxygen, but after adding CO2 too, as well
The primary methods of reducing nitrogen oxides, despite the development of more advanced technologies, will continue to be the basis for NOx reduction. This paper presents the results of multivariate numerical studies on the impact of air staging on the flue gas temperature and composition, as well as on NOx emissions in a OP 230 boiler furnace. A numerical model of the furnace and the platen superheater was validated based on measurements using a 0-dimensional model of the boiler. Numerical simulations were performed using the ANSYS Workbench package. It is shown that changes in the distribution of air to OFA nozzles, the angle of the air outflow from the nozzles and the nozzle location involve a change in the flue gas temperature and in the volume of NOx and CO emissions at the furnace outlet.
In this work problems associated with requirements related to pollution emissions in compliance with more restrictive standards, low-emission combustion technology, technical realization of the monitoring system as well as algorithms allowing combustion process diagnostics are discussed. Results of semi-industrial laboratory facility and industrial (power station) research are presented as well as the possibility of application of information obtained from the optical fibre monitoring system for combustion process control. Moreover, directions of further research aimed to limit combustion process environmental negative effects are presented.
Due to the fact that the landfill deposition of municipal waste with the higher heating value (HHV) than 6 MJ/kg in Poland is prohibited, the application of waste derived fuels for energy production seems to be good option. There is a new combined-heat-and-power (CHP) plant in Zabrze, where varied solid fuels can be combusted. The formation of ashes originating from the combustion of alternative fuels causes a need to find ways for their practical application and demands the knowledge about their properties. Therefore, the present work is devoted to studying the co-combustion of solid recovered fuel (SRF) and coal, its impact on fly ash quality and the potential application of ashes to synthesis zeolites. The major objectives of this paper is to present the detail characteristics of ash generated during this process by using the advanced instrumental techniques (XRF, XRD, SEM, B ET, TGA). The co-combustion were carried out at 0.1 MWth fluidized bed combustor. The amount of SRF in fuel mixture was 1, 5, 10 and 20%, respectively. The focus is on the comparison the ashes depending on the fuel mixture composition. Generally, the ashes characterise high amounts of SiO2, Al2O3 and Fe2O3. It is well observed, that the chemical composition of ashes from co-combustion of blends reflects the amount of SRF addition. Considering the chemical composition of studied ashes, they can be utilize as a zeolites A. The main conclusions is that SRF can be successfully combusted with coal in CFB technology and the fly ashes obtained from coal + SRF fuel mixtures can be used to synthesis zeolites.
Results of the study examining carbon monoxide and nitric oxide concentrations while burning different types of agricultural biomass: coffee husk pellets alone or in combination with wheat straw pellets and cherry stones, sewage sludge pellets, corn stover briquettes and a mixture of rye straw briquettes and miscanthus briquettes were presented. The combustion was performed in a 50 kW boiler type Biowarmer with a cast-iron moving step grate. The temperature in the combustion chamber did not exceed 800 ◦C. For all biomass types, only brittle slag was generated in the furnace, which was easily broken by a reciprocating movement of the grate. Carbon monoxide concentration in the flue gas except for the case of sewage sludge pellet firing did not exceed the permitted value of 3000 mg/m3 and nitric oxide concentration 515 mg/m3, both presented for 10% O2 concentration in the flue gas based in dry gas. Hydrocarbon concentrations for all test runs were close to zero.
The work contains a description of a developed experimental and theoretical method of modeling of solid waste combustion in a device equipped with a moving grate and capability to optimize the work of waste incineration plant. Implementation of this issue was based on results of experimental studies made on a laboratory scale boiler. This was possible by defining and testing indicators of quantitative assessment of combustion such as: reaction front rate, ignition rate, the rate of combusted mass loss and the heat release rate. These indicators as measurable "criteria indicators" allow transfer of parameters from a laboratory-scale unit, working in the transient regime into an industrial full scale grate device working continuously in stable determined conditions. This allows for wide optimization possibilities in the operation of a waste incineration plant, in particular the combustion chamber, equipped with a moving grate system.
The present work focuses on analyses of the autoignition delay time predicted by the large eddy simulation (LES) method by applying different subgrid scales (SGS) models and two different discretization schemes. The analysed flow configuration is a two-phase chemically reacting turbulent flow with monodispersed evaporating fuel droplets. The impact of numerical procedure is investigated in a 3D flow domain with a temporally evolving mixing layer that constituted between the streams of fuel and oxidizer that moved in opposite directions. The upper stream of cold gas carries a dispersed fuel spray (ethanol at 300 K). The lower stream is a hot air at 1000 K. Three commonly used in LES, SGS models are investigated, namely: classical Smagorinsky model, model proposed by Vreman and the #27;-model proposed by Nicoud. Additionally, the impact of two discretization schemes, i.e., total variation diminishing (TVD) and weighted essentially nonoscillatory (WENO) is analysed. The analysis shows that SGS model and discretization scheme can play a crucial role in the predictions of the autoignition time. It is observed that for TVD scheme the impact of SGS model is rather small. On the contrary, when the WENO scheme is applied the results are much more dependent on the SGS model.
A catalytic combustion of organic admixtures of air belongs to the basic technologies of gas purification. A macrokinetics of admixtures combustion over the porous catalysts was described. The theoretical approach is in agreement with standard description of macrokinetics of the catalytic processes. The relationship between the fundamental magnitudes: observed process rate r*, reaction rate r in the kinetic zone, and a coefficient of the surface utilization η in the form r*= r · η have been described. These magnitudes combines the Thiele module φ. A kinetics equation for the isothermal and non-isothermal conditions was provided. The influence of mass and heat transfer in the catalyst grain on the course of the process was described by means of the surface utilization coefficient η. An equation describing this coefficient for both isothermal and non-isothermal conditions was given. The second part of this work concerns the application of theory. When the composition of purified gas is continuously varied, a quantitative approach is rather impossible. The theory was used for the qualitative analysis of process on the basis of the experimental results. A fulfillment of the first-order kinetics means that the degree of admixtures conversion does not depend on their initial concentrations. A non-isothermicity of the catalyst grain is expressed in such a way that the process rate observed over the large porous grains of the catalyst can be higher than the reaction rate in the kinetic zone. A temperature deference between the catalyst grains and flowing gas causes that the reactor can be stably operated at varied concentrations of admixtures and temperature over a relatively wide range. It was also demonstrated that the flammable admixtures may advantageously influence the conversion of hardly combustible admixtures
The aim of this research was to assess the content and composition of the pollutants emitted by domestic central heating boilers equipped with an automatic underfeed fuel delivery system for the combustion chamber. The comparative research was conducted. It concerned fuel properties, flue gas parameters, contents of dust (fl y ash) and gaseous substances polluting the air in the flue gases emitted from a domestic CH boiler burning bituminous coal, pellets from coniferous wood, cereal straw, miscanthus, and sunflower husks, coniferous tree bark, and oats and barley grain. The emission factors for dust and gaseous air pollutants were established as they are helpful to assess the contribution of such boilers in the atmospheric air pollution. When assessing the researched boiler, it was found out that despite the development in design and construction, flue gases contained fly ash with a significant EC content, which affected the air quality.
The paper presents current reports on kinetics and mechanisms of reactions with mercury which take place in the exhaust gases, discharged from the processes of combustion of solid fuels (coals). The three main stages were considered. The first one, when thermal decomposition of Hg components takes place together with formation of elemental mercury (Hg0). The second one with homogeneous oxidation of Hg0 to Hg2+ by other active components of exhaust gases (e.g. HCl). The third one with heterogeneous reactions of gaseous mercury (the both - elemental and oxidised Hg) and solid particles of fl y ash, leading to generation of particulate-bound mercury (Hgp). Influence of exhaust components and their concentrations, temperature and retention time on the efficiency of mercury oxidation was determined. The issues concerning physical (gas-solid) and chemical speciation of mercury (fractionation Hg0-Hg2+) as well as factors which have influence on the mercury speciation in exhaust gases are discussed in detail.
According to data of the Central Statistical Ofﬁce, the amount of sludge produced in municipal wastewater treatment plants in 2010 amounted to 526000 Mg d.m. The forecast of municipal sewage sludge amount in 2015 according to KPGO2014 will reach 642400 Mg d.m. and is expected to increase in subsequent years. Signiﬁcant amounts of sludge will create problems due to its utilization. In order to solve this problem the use of thermal methods for sludge utilization is expected. According to the National Waste Management Plan nearly 30% of sewage sludge mass should be thermally utilized by 2022. The article presents the results of co-combustion of coal and municipal sewage sludge in a bubbling ﬂuidized bed boiler made by SEFAKO and located in the Municipal Heating Company in Morag. Four tests of hard coal and sewage sludge co-combustion have been conducted. Boiler performance, emissions and ash quality were investigated.
The author has developed and patented several types of gas cupola furnaces, which, due to replacing coke with gas, do not emit carbon monoxide, sulfur dioxide and coke dust. The author has defined the optimal modes of gas-and-air mixture combustion, i.e. the optimal coefficient of air discharge and gas mixture escape speed in melting cast iron. It has been experimentally proved that from the point of view of obtaining the maximum temperature, the optimal was the process with some lack of air, i.e. with α = 0.98. The results of metallurgical studies used in the article allowed to develop an optimal structure of the gas cupola furnace with a heterogeneous refractory filling, and to establish the optimal composition of the filling. For the first time the optimal composition of the filling is given: 40% of chamotte, 30% of high-alumina refractory, 30% of electrode scrap. It has been noted that when gas cupola furnaces were used, the main environmental advantage was the reduction of dust emission into the atmosphere, CO and SO2 content.
The work presents results of solution combustion method utilization for yttria (Y2O3) nanopowder fabrication. Experiments were carried out with four different reducing agents: urea, glycine, citric acid and malonic acid added in stoichiometric ratio. The reactions were investigated using simultaneous DSC/DTA thermal analysis. After synthesis the reaction products were calcined at temperature range of 800-1100°C and analyzed in terms of particle size, specific surface area and morphology. Best results were obtained for nanoyttria powder produced from glycine. After calcination at temperature of 1100°C the powder exhibits in a form of nanometric, globular particles of diameter <100 nm, according to SEM analysis. The dBET for thus obtained powder is 104 nm, however the powder is agglomerated as the particle size measured by dynamic light scattering analysis is 1190 nm (dV50).
Trace elements contained in coal escape with flue gas from energy sources into the air or move towards other components of the environment with by-products captured in electrofilters (EF) and flue gas desulphurisation (FGD) plants. The existing knowledge about the distribution of frequently dangerous trace elements contained in these products is insufficient. Studies were therefore undertaken in selected power plants to investigate the distribution of trace elements in coal, slag, as well as dust containment and flue gas desulphurisation products, such as fly ash captured in dust collectors, desulphurisation gypsum and semi-dry scrubbing FGD products. Using the technique of flame atomic absorption spectrometry (F-AAS) and mercury analyser, the following were determined in the research material samples: Cr, Cu, Hg, Mn, Ni, Pb and Zn. The studies have a reconnaissance character. The authors have presented the results of determinations for selected trace elements in samples taken at Jaworzno III and Siersza Power Plants, which burn hard coal, and in Bełchatów Power Plant, burning brown coal. A balance of the examined trace elements in a stream of coal fed into the boiler and in streams of waste and products carried away from the plant was prepared. The balance based on the results of analyses from Bełchatów Power Plant was considered encouraging enough to undertake further investigations. The research confirmed that due to the distribution in the process of coal combustion and flue gas treatment, a dominant part of particular trace elements’ stream moves with solid waste and products, while air emission is marginal. Attention was paid to the importance of research preparation, the manner of sample taking and selection of analytical methods.
The aim of the study was to evaluate the effect of pre-sowing seed stimulation of Thuringian Mallow (Lavatera thuringiaca L.) with He-Ne laser light of different exposure times on the crop yield as well as on energetic parameters such as calorific value and combustion heat. Seeds were subjected to laser light with an exposition time of 0, 1, 5, 10, 15 and 30 minutes. Measurements were carried out independently on mature plants from the first and second vegetation year. The results varied between the samples, which indicated possible impact of laser radiation on the resultant weight and calorific value of various experimental combinations. For plants from the second vegetation year the statistical differences in calorific value, combustion heat and crop mass were found between samples characterized by different exposition times: between sample irradiated for 30 min (L30) and 1 min (L1) as well as between sample L30 and sample irradiated for 5 minutes (L5). For plants after the first vegetation year the statistically significant differences in calorific value and combustion heat were found for sample with exposition time of 15 minutes (L15) and control sample, for sample L15 and sample L5 as well as between samples L15 and L30. For all the samples from the second vegetation year the increase in combustion heat and calorific values were detected as compared to control. Thus, after the application of certain parameters of laser radiation to the processing of seeds, the plant can be more useful for energetic purposes through more efficient crop.
It has been found that the vegetable oils are promising substitute, because of their properties are similar to those of diesel fuel and they are renewable and can be easily produced. However, drawbacks associated with crude vegetable oils are high viscosity, low volatility call for low heat rejection combustion chamber, with its significance characteristics of higher operating temperature, maximum heat release, and ability to handle lower calorific value (CV) fuel etc. Experiments were carried out to evaluate the performance of an engine consisting of different low heat rejection (LHR) combustion chambers such as ceramic coated cylinder head-LHR-1, air gap insulated piston with superni (an alloy of nickel) crown and air gap insulated liner with superni insert - LHR-2; and ceramic coated cylinder head, air gap insulated piston and air gap insulated liner - LHR-3 with normal temperature condition of crude rice bran oil (CRBO) with varied injector opening pressure. Performance parameters (brake thermal efficiency, brake specific energy consumption, exhaust gas temperature, coolant load, and volumetric efficiency) and exhaust emissions [smoke levels and oxides of nitrogen [NOx]] were determined at various values of brake mean effective pressure of the engine. Combustion characteristics [peak pressure, time of occurrence of peak pressure, maximum rate of pressure rise] were determined at full load operation of the engine. Conventional engine (CE) showed compatible performance and LHR combustion chambers showed improved performance at recommended injection timing of 27°bTDC and recommend injector opening pressure of 190 bar with CRBO operation, when compared with CE with pure diesel operation. Peak brake thermal efficiencyincreased relatively by 7%, brake specific energy consumption at full load operation decreased relatively by 3.5%, smoke levels at full load decreased relatively by 11% and NOx levels increased relatively by 58% with LHR-3 combustion chamber with CRBO at an injector opening pressure of 190 bar when compared with pure diesel operation on CE.
Y2O3-MgO nanocomposites are one of the most promising materials for hypersonic infrared windows and domes due to their excellent optical transmittance and mechanical properties. In this study, influence of the calcination temperature of Y2O3-MgO nanopowders on the microstructure, IR transmittance, and hardness of Y2O3-MgO nanocomposites was investigated. It was found that the calcination temperature is related to the presence of residual intergranular pores and grain size after spark plasma sintering. The nanopowders calcined at 1000°C exhibits the highest infrared transmittance (82.3% at 5.3 μm) and hardness (9.99 GPa). These findings indicated that initial particle size and distribution of the nanopowders are important factors determining the optical and mechanical performances of Y2O3-MgO nanocomposites.
A forecast of the negative impact exerted on the environment by selected trace elements in “Bełchatów” Power Plant has been prepared on the basis of the results of investigations into these elements’ distribution carried out as part of earlier research on coal from “Bełchatów” Field and the data on updated analyses of the content of these elements in 55 brown coal samples from test boreholes. Work in “Bełchatów” Power Plant, which is supplied with coal from “Szczerców” Field, will be accompanied by trace elements transfer. On the basis of the conducted investigations it has been found that the biosphere is most threatened by mercury emissions. As shown by the presented results of analyses and calculations, the emissions of mercury in “Bełchatów” Power Plant are low. Mercury is accumulated chiefl y in gypsum produced in the FGD plant. The content of mercury in slag and ash is low.