Strength and permeability properties along with microstructural evolution of hardened slurries composed of fly ash from fluidal bed combustion of brown coal and an addition of OPC/BFSC is assessed in this paper. An increase in the amount of fly ash in slurries influences the development of mechanical strength and a decrease of hydraulic conductivity. SEM, XRD, and porosity analyses confirmed formation of watertight microstructures. The structure of slurries is composed of ettringite, C-S-H phase, AFt, and AFm phases. Ettringite crystallises as relatively short needles forming compact clusters or intermixed with the C-S-H phase. The occurring C-S-H phases are mainly of type I – fibrous and type II – honeycomb
This article presents test results for hydraulic conductivity and porosity structure of hardening slurries prepared of Portland cement, betonite, water and fluidal ashes from the combustion of hard and brown coal. The slurries were exposed to persistent filtering action (180 days) of liquids chemically aggressive to cement binders, i.e. distilled water, 0.5% solution of nitric acid, 1% solution of sodium sulphate, 1% solution of magnesium nitrate and 1% solution of ammonium nitrate. Samples exposed to filtration of tap water constituted the reference base. The research was into relations between hydraulic conductivity and pore structure parameters in slurries, as well as into the influence of the type of aggressive medium on leak tightness of slurries (their porosity and hydraulic conductivity).
This article presents ways of possible utilization and application of fl uidal combustion wastes as active additives to hardening slurries which are used to seal environment protection structures, i.e. cut-off walls in waste dumps and wastewater treatment plants. Cut-off walls are often exposed to fi ltrating action of eluates - polluted (aggressive) waters. Results of hydraulic conductivity tests of slurries after their long-term (210 days) fi ltration with eluates from a municipal waste dump and with tap water are presented. Porosity tests were also conducted to show the porosity structure of the fi ltered slurries. Additionally, compressive strength of slurries maturing in tap water and waste dump eluates was tested in parallel.
Along with the increase in popularity of the sewage sludge thermal treatment methods in Poland resulting from the implementation of European Union law, a management problem with ash, which is produced as a result of this process, appeared. The paper analyses the chemical composition and physical properties of fl y ash from thermal treatment of municipal sewage sludge in terms of its use in concrete technologies in relation to EN 450-1 Fly ash for concrete. Defi nition, specifi cations and conformity criteria (2012) and EN 197-1 Cement. Composition, specifi cations and conformity criteria for common cements (2011) standards. The tested material did not meet the requirements related to use of fl y ash for concrete production (chemical composition, low activity index, high water demand and fi neness), and as main and minor components for cement production. On the basis of the carried out research and analyses, it was found that the hardening slurry technology creates the greatest possibilities related to the management of fl y ash from thermal treatment of municipal sewage sludge.