The paper presents an analysis of hard coal prices offered at the coal depots in Poland. Coal depots are one of the most popular forms of purchasing coal by Polish households. Prices refer to price offers for cobble coal (grain size: 60–120 mm) and their analysis is performed based on the regions rather than on all Polish provinces. From January 2010 to May 2019, there were two regions that were distinguished in terms of price spread: the S-W region and the N-E region. In the case of the S-W region, the difference between the province with the minimum price (Śląskie Province) and with the maximum price (Dolnośląskie Province since September 2017) ranged from PLN 53–83/ton, and in the N-E region the difference ranged PLN 64–130/ton. In the case of the remaining two regions, prices varied from a few to approximately PLN 80/ton for the N-W region, and from a few to about PLN 40 /ton for the S-E region. In order to determine how the origin of the coal affects its prices (domestic coal, imported coal), the analysis also included cobble coal price offers that are part of the Author’s own database created for several years. In the case of cobble coal from domestic producers, price offers varied betwwen PLN 14–33/GJ, and price offers for imported cobble coal stood varied between PLN 12–32/GJ. The N-E region attracted particular attention as the price offers for imported cobble coal reached a level similar to the offers from the S-W region, i.e. the region closest to Silesian coal mines. Price differentials within provinces belonging to a given region were influenced by the geographical rent. The paper also analyses average selling prices offered by domestic producers for various size grades of steam coal as well as selling prices for imported coal (free-at-frontier price).
Coal reserves in the Czech Republic are estimated to be 10 billion tons – hard coal about 37%, brown coal about 60% and lignite 3%. Hard coal is produced in Northern Moravia. In 2017 the production of hard coal was 5.5 million tons. Brown coal is mined in North-Western Bohemia − the production of brown coal in 2017 was 38.1 million tons. Significant quantities of hard coal are exported to: Slovakia, Austria, Germany and Hungary. In accordance with the National Energy Policy, coal will remain the main source of energy in the country in the future, despite the increased use of nuclear energy and natural gas. The government expects that in 2030 energy from coal will account for 30.5% of energy produced. There are five coal companies in the Czech Republic: OKD, a.s., the only hard coal producer and four brown coal mining companies: Severočeské Doly a.s., owned by ČEZ, the largest producer of brown coal, Vršanská uhelná a.s., with coal resources until 2055, Severní energetická a.s. with the largest brown coal reserves in the Czech Republic and Sokolovska uhelná a.s., the smallest mining company extracting lignite. OKD operates coal in two mines Kopalnia Důlní závod 1 – (consists of three mines: ČSA Mine, Lazy Mine, Darkov Mine) and Mine Důlní závod 2 (ttwo mines Sever, Jih). The article also presents a pro-ecological solution for the management of waste heaps after coal enrichment – a plant for the enrichment of coal waste from the Hermanice heap.
Coal combustion processes are the main source of mercury emission to the environment in Poland. Mercury is emitted by both power and heating plants using hard and brown coals as well as in households. With an annual mercury emission in Poland at the level of 10 Mg, the households emit 0.6 Mg. In the paper, studies on the mercury release in the coal and biomass combustion process in household boilers were conducted. The mercury release factors were determined for that purpose. For the analyzed samples the mercury release factors ranged from 98.3 to 99.1% for hard coal and from 99.5% to 99.9% for biomass, respectively. Due to the high values of the determined factors, the amount of mercury released into the environment mainly depends on the mercury content in the combusted fuel. In light of the obtained results, the mercury content in the examined hard coals was 6 times higher than in the biomass (dry basis). Taking the calorific value of fuels into account, the difference in mercury content between coal and biomass decreased, but its content in coal was still 4 times higher. The mercury content determined in that way ranged from 0.7 to 1.7 μg/MJ for hard coal and from 0.1 to 0.5 μg/MJ for biomass, respectively. The main opportunity to decrease the mercury emissions from households is offered by the use of fuels with a mercury content that is as low as possible, as well as by a reduction of fuel consumption. The latter could be obtained by the use of modern boilers as well as by the thermo-modernization of buildings. It is also possible to partially reduce mercury emissions by using dust removal devices.
The aim of this study was to determine to what extent the ions present in hard water (125 mg/L of MgCl2 and 500 mg/L of CaCl2) may intensify the feed-induced decrease in oxytetracycline (OTC) absorption rate in broiler chickens after single oral administration at a dose of 15 mg/kg. Drug concentrations in plasma were determined by liquid chromatography-tandem mass spectrometry and combined, compartmental and non-compartmental approach was used to assess OTC pharmacokinetics. The administration of feed decreased the absolute bioavailability (F) of OTC from 12.70%±4.01 to 6.40%±1.08, and this effect was more pronounced after the combined administration of OTC with feed and hard water (5.31%±0.90). A decrease in the area under the concentration- time curve (AUC0-t), (from 10.18±3.24 μg·h/ml in control to 5.13 μg·h/ml±1.26 for feed and 4.26 μg·h/ml±1.10 for feed and hard water) and the maximum plasma concentration of OTC (Cmax) (from 1.22±0.18 μg/ml in control, to 1.01 μg/ml ±0.10 for hard water, 0.68 μg/ml±0.10 for feed and 0.61 μg/ml±0.10 for feed and hard water) was observed. The results of this study indicate that feed strongly decreases F, AUC0-t and Cmax of orally administered OTC. The ions present in hard water increase this inhibitory effect, which suggests that, therapy with OTC may require taking into account local water quality and dose modification, particularly when dealing with outbreaks caused by less sensitive microorganisms.
The objective of the submitted paper is to analyze the influence of the load on the calibration of micro-hardness and hardness testers. The results were validated by Measurement Systems Analysis (MSA), Analysis of Variance (ANOVA) and Z-score. The relationship between the load and micro-hardness in calibration of micro-hardness testers cannot be explained by Kick's Law (Meyer's index "n" is different from 2). The conditions of Kick's Law are satisfied at macro-hardness calibration, the values of "n" are close to 2, regardless of the applied load. The apparent micro-hardness increases with the increase of the load up to 30 g; the reverse indentation size effect (ISE) behavior is typical for this interval of the loads. The influence of the load on the measured micro-hardness is statistically significant for majority of calibrations.
The aim of the study is to determine the mercury content in hard coal, randomly taken from the USCB and in by-products of hard coal mining (fresh mining waste), i.e. aggregates (gangue) and hard coal sludge and mining waste from the Siersza dump (weathered waste). The 34 samples were intended for analysis. The total mercury content and the amount of mercury leaching from solid samples was determined. The percentage of the leaching form in the total element content, i.e. the level of mercury release from the material (leaching level), was also calculated. The amount of mercury leaching was determined by a static method using a batch test 1:10. The highest possibility of leaching mercury is characterized by weathered waste from the Siersza dump and slightly lower analyzed hard coal from the U pper Silesian Coal Basin (USCB). For hard coal samples, the total mercury content is between 0.0275–0.1236 mg/kg. However, the amount of mercury leaching from coal samples is 0.0008–0.0077 mg/kg. The aggregate is characterized by a higher total mercury content in the finest fraction 0–6 mm, within 0.1377–0.6107 mg/kg and much lower in the 80-120 mm fraction, within 0.0508–0.1274 mg/kg. The amount of elution is comparable in both fractions and amounts to 0.0008–0.0057 mg/kg. Coal sludge has a total mercury content of 0.0937–0.2047 mg/kg. L ow leaching values of 0.0014–0.0074 mg/ kg are also observed. Weathered mining waste has a total mercury content of 0.0622–0.2987 mg/kg. However, leaching values from weathered waste are much higher than from fresh mining waste. This value is 0.0058–0.0165 mg/kg. In the hard coal extracted from U SCB, the leaching level is 4.7% on average. Mining waste is characterized by a large variation in the proportion of mercury leaching form and the differences result from the seasoning time of the samples. Waste or by-products of hard coal production, such as aggregates and coal sludge, show a mercury washout form at an average level of 1.7%. The proportion of leachable form in weathered waste increased strongly to 7.3%. Elution characteristics vary for different groups of materials tested. Factors such as the type and origin of samples, their granulometric composition and the seasoning time of the material are of fundamental importance and demonstrated in the work.
The Polish power generation system is based mostly on coal-fired power plants. Therefore, the coal mining sector is strongly sensitive to changes in the energy sector, of which decarbonization is the crucial one. The EU Emission Trading System (EU ETS) requires power generating companies to purchase European Emission Allowances (EUAs), whose prices have recently soared. They have a direct impact on the cost efficiency of hard coal-fired power generation, hence influence the consumption of hard coal on the power sector. In this context, the objective of this paper is to estimate the hard coal consumption in various regions of Poland under selected forecasts of the EUA price. To investigate this question, two models are employed: - the PolPower_LR model that simulates the Polish power generation system, - the FSM _LR model that optimizes hard coal supplies. Three scenarios differentiated by the EUA price are designed for this study. In the first one, the average EUA price from 2014–2017 is assumed. In the second and third, the EUA prices are assumed accordingly to the NPS and the SDS scenario of the World Energy Outlook. In this study we consider only existing, modernized, under construction and announced coal-fired power generation units. The results of the study indicate that regardless of the scenario, a drop in hard coal consumption by power generation units is observed in the entire period of analysis. However, the dynamics of these changes differ. The results of this analysis prove that the volume of hard coal consumption may differ by even 136 million Mg (in total) depending on the EUA prices development scenario. The highest cumulated volume of hard coal consumption is observed in the Opolski, Radomski and Sosnowiecki region, regardless of the considered scenario.
The coal fed to gravity enrichment consists of coals coming from different deposits and exploitation fronts. These coals differ in quality parameters, especially the amount of gangue (stone) changing over time. This results in the instability of work, especially jiggers, which have a relatively low accuracy assessed by probable scattering or imperfection rates. This deteriorates the quality of the concentrate obtained, the quality parameters of which change over time. The improvement of jiggers work would be possible by averaging the feed. This process is practically impossible due to the failure to design such a node during plant construction, which are, in most cases, directly related to the shaft. In the article, the authors propose to solve the process of averaging the feed before directing it to the enrichment process in jiggers by introducing its deshaling in vibratory- air separators of the FGX type.
Coal mining is one of the most important sectors of the Polish industry. It can be said that the coal is a national raw material. This results in Poland being a pioneer in the European Union in terms of coal mining as well as its use in the production of electricity and heat. There are many companies in Poland which have been established and developed around the coal mining industry aimed at coal extracting. The operations of those companies depends on the condition of the mining companies and their cooperation with them: commercial, service and advisory, called referred to as “mining supporting companies”. The article focuses on the results of a survey carried out in mining supporting companies, such as mining machinery and equipment manufacturers, mining-related service companies and mining-related research and development institutions. The authors evaluated the relationship and dependence of those companies on the mining industry. It was assumed that the measure of the mining supporting companies condition is the overall quantity of public related payments contributed to the state budget and local budgets. In the article, the authors raised the problem of the size of losses for public finances, as a result of the significant limitations of financial flows from the mining companies. The surveyed companies are those associated with the Polish Mining Chamber of Industry and Commerce. As a result, the authors prepared conclusions regarding the dependence of the mining supporting companies on the situation of the mining subsector.
In the processes of coal mining, preparation and combustion, the rejects and by-products are generated. These are, among others, the rejects from the coal washing and dry deshaling processes as well as the coal combustion by-products (fly ash and slag). Current legal and industry regulations recommend determining the content of mercury in them. The regulations also define the acceptable content of mercury. The aim of the paper was to determine the mercury content in the rejects derived from the coal cleaning processes as well as in the combustion by-products in respect of their utilization. The mercury content in the representative samples of the rejects derived from the coal washing and dry deshaling processes as well as in the coal combustion by products derived from 8 coal-fired boilers was determined. The mercury content in the rejects from the coal washing process varied from 54 to 245 μg/kg, (the average of 98 μg/kg) and in the rejects from the dry deshaling process it varied from 76 to 310 μg/kg (the average of 148 μg/kg). The mercury content in the fly ash varied from 70 to 1420 μg/kg, (the average of 567 μg/kg) and in the slag it varied from 8 to 58 μg/kg (the average of 21 μg/kg). At the moment, in light of the regulations from the point of view of mercury content in the rejects from the coal preparation processes and in the coal combustion by-products, there are no significant barriers determining the way of their utilization. Nevertheless, in the future, regulations limiting the maximum content of mercury as well as the acceptable amount of leachable mercury may be introduced. Therefore, preparing for this situation by developing other alternative methods of using the rejects and by-products is recommended.
The paper presents selected issues related to the development of international coal markets. World consumption of coal dropped for the second year in a row in 2016, primarily due to lower demand from China and the U S. The share of coal in global primary energy consumption decreased to 28%. World coal production accounted to 3.66 billion toe and it was lower by 6.2% when compared to the previous year. More than 60% of this decline took place in China. The decline in global production was more than four times higher than the decrease in consumption. The sufficiency of world resources of coal are estimated at 153 years – that is three times more than the sufficiency of oil and gas resources. After several years of decline, coal prices increased by 77% in 2016. The current spot prices are at the level of $80/t and are close to the 2014 prices. In the European market, after the first half of the year, coal prices reached the level of around 66% higher than in the same period of the last year. The average price in the first half amounted to PLN 12.6/GJ, which is close to the 2012 prices. The share of spot trade in the total purchase amount accounted to approx. 20%. Prices in futures contracts can be estimated on the basis of the Japan-Australia contracts prices and prices in supplies to power plants located in Germany. On average, the prices in supplies to these power plants were higher by approximately 9% in the years 2010–2016 and prices in Australia – Japan contracts were 12% higher than CIF ARA prices in 2017. Global energy coal trade reached about 1.012 billion tonnes in 2016. In 2019, a decline by 4.8% is expected primarily due to the expected reduction in the demand in major importing countries in Asia.
An analysis has been carried out of the influence of annealing time at the preheating temperature of 650 °C on the change in hardness and alloy structure of lamellar graphite cast iron in the working as well as in the laboratory conditions. This preheat temperature is common during reclaiming welding of castings with complex shapes. The changes in unalloyed cast iron EN-GJL 200 to EN-GJL 300 according to ISO 1690 standard and cast iron with low amount of elements such as Sn, Cu, Cr, and Mo and their combinations were assessed. It was found that the cast iron of higher strength grades has better hardness and structural stability. Cast iron alloyed with chromium or its combinations has the highest stability. In unalloyed cast iron, a partial degradation of pearlite occurs; in alloyed cast iron the structural changes are not conclusive.
The role of the hard coal mining sector in ensuring energy security of the country has been presented in the paper. An analysis of its current status was made based on the results obtained by the sector in 2017. Moreover, the determinants which are the precondition for further sustainable and efficient operation in the years to come have been defined.
Modern metal forming processes of non-ferrous metals, particularly aluminum and its alloys, are increasingly based on integrated technologies combining numerous operations in one process line. The subject of this paper focuses on the possibility of using materials after mould casting (simulating a continuous casting process between cylindrical crystallizers – Twin Roll Casting method) for the direct cold rolling process. As a part of this research a pilotage study on metallurgical synthesis and mould casting process of Al-Mg alloys with the magnesium contents of 5%-10%, testing their mechanical, electrical and structural properties as well as susceptibility to cold plastic deformation. This process was carried out with the measurement of strength parameters and confirmed the possibility of cold rolling alloys with a casting structure without prior hot deformation.
The implementation of EU environmental regulations in the energy sector is challenging for the power industry of its member states. The main role is played by documents such as the Winter Package and, especially, the Directive of the European Parliament and of the Council on the emission limits of certain pollutants and the implementation of BAT conclusions in order to achieve the EU’s decarbonization objectives. These regulations impose a greater need to control harmful substances emitted to the atmosphere while using fossil fuels, including hard coal, which is the main fuel for domestic units. At the same time, the decline in domestic fossil fuel production and decrease in the quality of parameters of the hard coal makes it difficult to purchase the proper fuel for power plants. As a consequence, the costs of hard coal increase. The article presents the concept of a mathematical model that can be applied for the optimization of coal supplies. The employment of this model allows one to achieve cost reductions. One of the advantages of the proposed tool, in addition to minimizing the cost of purchase and use of hard coal, is its rational management, especially for companies producing and using hard coal.
Mechanical properties and residual stresses of friction stir welded and autogenous tungsten inert gas welded structural steel butt welds have been studied. Friction stir welding (FSW) of structural steel butt joints has been carried out by in-house prepared tungsten carbide tool with 20 mm/ min welding speed and 931 rpm tool rotation. Tungsten inert gas (TIG) welding of the butt joints was carried out with welding current, arc voltage and the welding speed of 140 amp, 12 V and 90 mm/min respectively. Residual stress measurement in the butt welds has been carried out in weld fusion zone and heat affected zone (HAZ) by using blind hole drilling method. The magnitude of longitudinal residual stress along the weld line of TIG welded joints were observed to be higher than friction stir welded joint. In both TIG and FSW joints, the nature of longitudinal stress in the base metal was observed to be compressive whereas in HAZ was observed to be tensile. It can be stated that butt welds produced with FSW process had residual stress much lower than the autogenous TIG welds.
Improvement of Al-Si alloys properties in scope of classic method is connected with change of Si precipitations morphology through: using modification of the alloy, maintaining suitable temperature of overheating and pouring process, as well as perfection of heat treatment methods. Growing requirements of the market make it necessary to search after such procedures, which would quickly deliver positive results with simultaneous consideration of economic aspects. Presented in the paper shortened heat treatment with soaking of the alloy at temperature near temperature of solidus could be assumed as the method in the above mentioned understanding of the problem. Such treatment consists in soaking of the alloy to temperature of solutioning, keeping in such temperature, and next, quick quenching in water (20 0 C) followed by artificial ageing. Temperature ranges of solutioning and ageing treatments implemented in the adopted testing plan were based on analysis of recorded curves from the ATD method. Obtained results relate to dependencies and spatial diagrams describing effect of parameters of the solutioning and ageing treatments on HB hardness of the investigated alloy and change of its microstructure. Performed shortened heat treatment results in precipitation hardening of the investigated 320.0 alloy, what according to expectations produces increased hardness of the material.
Mechanical properties of aluminum-silicon alloys are defined by condition of alloying components in the structure, i.e. plastic metallic matrix created from solid solution on the basis of Al, as well as hard and brittle precipitations of silicon. Size and distribution of silicon crystals are the main factors having effect on field of practical applications of such alloys. Registration of crystallization processes of the alloys on stage of their preparation is directly connected with practical implementation of crystallization theory to controlling technological processes, enabling obtainment of suitable structure of the material and determining its usage for specific requirements. An attempt to evaluate correlation between values of characteristic points laying on crystallization curves and recorded with use of developed by the author TVDA method (commonly denominated as ATND method) is presented in the paper together with assessment of hardness of tested alloy. Basing on characteristic points from the TVDA method, hardness of EN AC-AlSi9Mg alloy modified with strontium has been described in the paper in a significant way by the first order polynomial.
The welding technologies are widely used for design of protection layer against wear and corrosion. Hardfacing, which is destined for obtaining coatings with high hardness, takes special place in these technologies. One of the most effective way of hardfacing is using self shielded flux cored arc welding (FCAW-S). Chemical composition obtained in flux cored wire is much more rich in comparison to this obtained in solid wire. The filling in flux cored wires can be enriched for example with the mixture of hard particles or phases with specified ratio, which is not possible for solid wires. This is the reason why flux cored wires give various possibilities of application of this kind of filler material for improving surface in mining industry, processing of minerals, energetic etc. In the present paper the high chromium and niobium flux cored wire was used for hardfacing process with similar heat input. The work presents studies of microstructures of obtained coatings and hardness and geometric properties of them. The structural studies were made with using optical microscopy and X- ray diffraction that allowed for identification of carbides and other phases obtained in the structures of deposited materials. Investigated samples exhibit differences in coating structures made with the same heat input 4,08 kJ/mm. There are differences in size, shape and distribution of primary and eutectic carbides in structure. These differences cause significant changes in hardness of investigated coatings.
The work presents the test result of the influence of cooling rate on the microstructure of AZ91 alloy, Vickers micro-hardness and Brinell hardness. Studies cooling and crystallization of AZ91 alloy was cast into the ceramic shells pre-heated to 180 ° C and then air-cooled at ambient temperature or intensively super cooled in the liquid coolant. The TDA method was applied to record and characterize the thermal effect resulting from the phase transformations occurring during the crystallization of AZ91 alloy. The kinetics and dynamics of the thermal processes of crystallization of AZ91 alloy in the ceramic shells were determined. Metallographic tests were performed with the use of an optical microscope. A comparison of these test results with the thermal effect recorded by way of the TDA method was made. Influence of cooling rate of AZ91 on HV0, 01 micro-hardness and Brinell hardness alloy was examined.
Repeated austenitisation and furnace cooling of homogenised 0.16 wt. % carbon steels result in ferrite grain sizes between 27 μm and 24 μm. Similarly, repeated austenitisation and normal-air cooling produces ferrite grain sizes between 17 μm and 12 μm; while repeated austenitisation and forced-air cooling produces a minimum grain size of 9.5 μm. Furnace cooling decomposes the austenite eutectoidally to lamellar pearlite; while normal-air cooling and forced-air cooling after austenitisation cause degeneration of pearlite regions producing grain boundary network as well as cluster of cementite and other carbides. Forced-air cooled samples provide the highest YS (364 MPa) and UTS (520 MPa); while furnace cooling provides the lowest (290 MPa and 464 MPa) leaving the normal-air cool performance in between. Hardness values depict the role of individual ferrite and pearlite content and the extent of pearlite degeneration occurring after each cyclic treatment.
In the present paper, the effects of the subsequent extrusion after multi-pass equal-channel angular pressing (ECAP) process on the mechanical properties and microstructure of WE43 magnesium alloy are investigated. First, second and fourth passes ECAP followed by an extrusion process are applied on WE43 magnesium alloy to refine the microstructure and to improve the mechanical properties for biomedical applications. The results showed that among the ECAPed samples, the highest and lowest strength were obtained in the second and the first pass processed samples, respectively. The four passes processed sample showed the highest elongation to failure with moderate strength. The sample processed via first pass ECAP followed by extrusion exhibits an excellent combination of ductility and strength. The highest strength was obtained in the sample processed via the second pass ECAP followed by extrusion while the highest elongation was achieved in the sample processed via fourth pass ECAP followed by extrusion. Moreover, Vickers micro-indentation tests demonstrate that hardness is enhanced by an increase in the number of ECAP passes. Furthermore, a grain refinement process is presented for ECAP processing of WE43 alloy which shows a good agreement with microstructural investigations.
This paper analyses the heat treatment of the hot-dip zinc coating deposited on both cast iron and steel. The aim of research is to increase coating hardness and wear resistance without decreasing its anticorrosion properties. Hot-dip zinc coating was deposited in industrial conditions (acc. PN-EN ISO 10684) on disc shape samples and bolts M12x60. The achieved results were assessed on the basis of microscopic observation (with the use of an optical and scanning microscope), EDS (point and linear) analysis and micro-hardness measurements. It was discovered that the heat treatment of zinc coating results in an increase in hardness which is caused by the corresponding changes in microstructure.
The aim of the performed experiments was to determine the influence of deformation and of austenitization temperature on the kinetics of phase transformations during cooling of high-carbon steel (0.728 wt. % C). The CCT and DCCT diagrams for austenitization temperature 940°C and DCCT diagram for austenitization temperature 1000°C were constructed with the use of dilatometric tests. On the basis of obtained results, a featureless effect of austenitization temperature and deformation on the kinetics of phase transformations during cooling of investigated steel was observed. Critical cooling rates for the transformation of martensite in microstructure fluctuated from 5 to 7°C · s–1 (depending on the parameters of austenitization and deformation), but only at cooling rates higher than 8°C · s–1 a dominant share of martensite was observed in the investigated steel, which resulted in the significant increase of hardness.