The possibility of the application of nontraditional method of greenhouse gas utilization by the injection of CO2 (sequestration) into porous geological deposits, treated as unconventional gas collectors, requires the fulfillment of basic criteria such as the impact on the environment and long term storage. The important issue is the physical behavior of the deposit during the porous structure saturation phase by carbon dioxide. What should be mentioned first and foremost is: the availability of CO2 transport along the porous structure and adsorption capacity. The work presents the results of water vapor sorption on coal samples from selected Hard Coal Mines of a differentiated carbon content. The received results were presented in the form of sorption and desorption isotherms performed in a temperature of 303 K. It was additionally described with a BET adsorption isotherm. Based on sorption data, a specific surface area was calculated, in accordance with BET theory. The amount of the adsorbed water vapor molecules for the analyzed coal samples was dependent on the degree of metamorphism. The obtained isotherms can be described as type II according to the BET classification. Volumetric type apparatus -adsorption- microburette liquid was used for the sorption experiments. Water vapor sorption in relation to coals allows for the quantitative determination of primary adsorption centers as a measure of adsorbed molecule interconnections with the adsorbent surface. Based on the BET adsorption equation, out of water vapor isotherms, the amount of adsorption active centers, which potentially may take part in CO2 adsorption in coal seams during injection of this gas, was determined. The sorption capacity of coals is determined by the degree of metamorphism, which also has very large impact on the sorption capacity of the deposit.
The present study examines some durability aspects of ambient cured bottom ash geopolymer concrete (BA GPC) due to accelerated corrosion, sorptivity, and water absorption. The bottom ash geopolymer concrete was prepared with sodium based alkaline activators under ambient curing temperatures. The sodium hydroxide used concentration was 8M. The performance of BA GPC was compared with conventional concrete. The test results indicate that BA GPC developes a strong passive layer against chloride ion diffusion and provides better protection against corrosion. Both the initial and final rates of water absorption of BA GPC were about two times less than those of conventional concrete. The BA GPC significantly enhanced performance over equivalent grade conventional concrete (CC).