The impacts of industrial wastewater contamination on the geotechnical properties of clayey soil have been studied in the research presented in this paper. The contaminant in question is industrial wastewater released from Thi-Qar oil refinery as a by-product of production, and the soil samples obtained from Thi-Qar oil refinery plant in Al-Nassyriah (a city located in the south of Iraq). The geotechnical properties of contaminated soil samples were compared with those of intact soil to measure the effects of such a contaminant. The soil samples were obtained from three locations in the study area; representing the highly contaminated area, the slightly contaminated area, and the intact area used as a reference for comparison of test results. The results of the tests showed that the contaminant causes an increase of natural moisture content, field unit weight, Atterberg’s limits, and maximum dry unit weight, as well as an increase of the compression index and the coefficient of vertical consolidation. Also, the contaminant causes a decrease in specific gravity, the optimum moisture content initial void ratio, the swelling index, the coefficient of permeability, and cohesion between soil particles.
The aim of the research was the evaluation of wastewater management in terms of stability and efficiency of wastewater treatment, using statistical quality control. For this purpose, the analysis of the operation and operation of the “Kujawy” Sewage Treatment Plant was made, which is one of the most important and largest sewage management facilities in the city of Cracow. This assessment was done using control charts x for 59 observations. The analysed research period covered the multi-year from 2012 to 2016. Five key pollutant indicators were used to evaluate the work of the tested object: BOD5, CODCr, total suspension, total nitrogen and total phosphorus. In the case of the majority of them, based on the analysis of control charts, full stability of their removal was found in the tested sewage management facility. The exception was total nitrogen, for which periods of disturbed stability of its disposal processes were noted. Analysis of the effectiveness of wastewater treatment showed each time that the required efficiency of reduction of the analysed pollution indicators in the “Kujawy” Sewage Treatment Plant was achieved.
Biochemical Oxygen Demand (BOD) is an important factor used to measure water pollution. This article reviews recent developments of microbial biosensors with respect to their applications for low BOD estimation. Four main methods to measure BOD using a biosensor are described: microbial fuel cells, optical methods, oxygen electrode based methods and mediator-based methods. Each of them is based on different principles, thus a different approach is required to improve the limit of detection. A proper choice of microorganisms used in the biosensor construction and/or sample pre-treatment processes is also essential to improve the BOD lower detection limit.
The primary objective of the present study was to determine the seasonal dynamics of ciliates in activated sludge. Studies were carried out in order to verify the hypothesis that fertility of a habitat may significantly influence the seasonal dynamics of the abundance of ciliates, as well as the number and intensity of correlations between physic-chemical parameters and ciliates. It seems that the values of numbers of ciliates were seasonally changeable. The highest numbers of ciliates were found in spring and summer, however the lowest numbers of ciliate communities were noted in winter. The studies showed that protozoa community is determined by ammonia mainly in summer. In spring and winter additional factors may be important. Probably suspended solid, total organic carbon and concentration of appropriate food (bacteria and flagellates) are the major regulator of abundance of ciliates.
The aim of the study was to determine the impact of various methods of oil mixing with wastewater on properties of synthetic municipal wastewater containing edible oil (SMW+0.02% m/v rapeseed oil). The study was carried out in 3L glass, cylindrical reactors to which SMW+0.02% were introduced. Various methods of its mixing with water were applied: mechanical mixing (SMW+0.02%+mixing) and sonication (SMW+0.02%+ultrasounds). The wastewater was sonicated at 35 kHz for 30 min. The constant temperature conditions were maintained during the experiment for each mixing method (15°C, 20°C and 30°C). The analysis of parameters (pH, COD, BOD5 and long chain free fatty acids concentration) of raw wastewater and after 2, 4, 6, 24, 48 and 72 hours of inoculation was performed to determine the effect of mixing method. The most signifi cant changes in wastewater chemical parameters after the introduction of the oil were observed in the case of COD. For SMW+0.02%+ mixing a slow increase in COD within 24 hours of the process was observed. In the case of SMW+0.02%+ultrasounds the increase and the decrease of COD value were observed in reference to the initial value. The changes in acids concentrations observed in reactors with SMW+0.02%+ultrasounds were referred to the ones observed in reactors with SMW+0.02%+mixing but changes were more intense in the fi rst reactor. The use of ultrasounds in pre-treatment of wastewater resulted in the intense appearance of palmitic acid for 6 hours. Regardless of the emulsion formation method (mixing or ultrasounds), the concentration of oleic acid and linoleic acid was reduced. The biggest changes in free fatty acids concentration were observed for palmitic, oleic and linoleic acids after 24 hours.
The paper presents the results of studies on the changes in the PAHs concentration during pre-filtration and ultrafiltration (UF) processes. In the study, biologically treated wastewater (after denitrification and nitrification processes), discharged from the biological treatment plant and used in coke plant, was used. A gas chromatography-mass spectrometry (GC-MS) was used in order to qualify and quantify the PAHs. Sixteen PAHs listed by EPA were determined. The wastewater samples were collected three fold and initially characterized for the concentration of nitrate nitrogen, ammonium nitrogen, COD, TOC and pH. In the first step, wastewater was filtrated on the sand bed. Total concentration of 16 PAHs in the treated wastewater before initial filtration was in the range of 44.8‒53.5 mg/L. During the process the decrease in the concentration of the most studied hydrocarbons was observed. Concentration of PAHs after initial filtration ranged from 21.9 to 38.3 μg/L. After the initial filtration process the wastewater flew to the ultrafiltration module and then was separated on the membrane (type ZW-10). The total concentration of 16 PAHs in the process of ultrafiltration was in the range of 8.9‒19.3 mg/L. The efficiency of removal of PAHs from coke wastewater in the process of ultrafiltration equaled 66.6%. Taking into account the initial filtration, the total degree of removal of PAHs reached 85%. The obtained results indicate the possibility of using the ultrafiltration process with the initial filtration as additional process in the coke wastewater treatment.
In the paper toxicity assessment of hospital wastewaters samples was performed using direct-contact tests consisting of five species, which represent three different trophic levels of the food chain. IC50 or EC50 values were estimated for each tested organism: Pseudokirchneriella subcapitata IC50/72h 18.77%, Daphnia magna EC50/48h 20.76%, Thamnocephalus platyurus EC50/24h 22.62%, Artemia salina EC50/24h 59.87% and Vibrio fisheri EC50/15min 46.17%. Toxic potential of hospital wastewater was described using a system of wastewater toxicity classification. The toxic units (TU) values estimated for each test indicate that hospital wastewaters are toxic (Class III). The variable results of the tests’ sensitivity confirmed the need of application of microbiotests battery with organisms of different trophic levels.
Sewage and solid waste can be a valuable source of materials used directly or indirectly in manufacturing of usable products. These processes are associated with elimination of pollutants from liquid and solid wastes. The best-known methods of waste management are production of biogas and composting. This paper focuses on the possibility of obtaining biomass as a source of protein feed (whose value, in terms of the composition of aminoacids and microelements, is comparable with conventional feed, e.g. soymeal, bonemeal or fishmeal). Sewage components for bacterial, fungal, algal and vascular plants’ culture are characterized as a source of protein feed. Methods of industrial scale production of enzymes, mainly proteases and lipases that have broad applications in various industries, are discussed. Development perspectives of inexpensive methods of usable products from waste production are showed. Interdisciplinary nature of presented issues, which requires cooperation of specialists in biology, chemistry and technology, is emphasized.
The paper presents preliminary results of investigations on a relationship between turbidity and other quality parameters in the SBR plant effluent. The laboratory tests demonstrated a high correlation between an effluent turbidity and a total suspended solids (TSS) concentration as well as between TSS and COD. Such a relationship would help to continuously monitor and control quality of a wastewater discharge using turbidity measurement.
The aim of this study was to determine the impact of the temperature of wastewater in a biological reactor with activated sludge and the BOD5/N-NH4 ratio in the inﬂuent to the treatment plant on nitriﬁcation efﬁciency and the concentration of ammonium nitrogen in treated wastewater. Tests were carried out in a household wastewater treatment plant which collects and treats sewage from a school building and a teacher’s house. During the 3-year study, large ﬂuctuations in the sewage temperature in bioreactor were noted which was closely related to the ambient temperature. There were also large ﬂuctuations in the concentration of organic matter and the concentration of ammonium nitrogen in inﬂowing sewage. The inﬂuence of wastewater temperature in the bioreactor and the BOD5/N-NH4 ratio on the concentration of ammonium nitrogen in treated wastewater was determined using Pearson’s linear correlation. A statistical analysis showed that a 1°C decrease in the temperature of wastewater in the bioreactor increased the concentration of ammonium nitrogen in treated wastewater by 2.64 mgN-NH4·L-1. Moreover, it was found that nitriﬁcation depended on the ratio of BOD5 to the concentration of ammonium nitrogen in wastewater ﬂowing into the bioreactor. An increase in the BOD5/N-NH4 ratio by 1 value led to a 5.41 mgN-NH4·L-1 decrease in the concentration of ammonium nitrogen.
Five cosmetics wastewater samples were treated by Dissolved Air Flotation (DAF) assisted by coagulation. Different aluminum based coagulants were used: (Al2(SO4)3, Al 1019, Al 3010, Al 3030, Al 3035, PAX 16 and PAX 19). The raw wastewater COD values were in the range 285-2124 mg/l. The efficiency of DAF depended on different coagulants and production profi le of factory. COD removal was varied from 11.1 to 77.7%. The efficiency of coagulants was similar during treatment of particular sample. The best results were obtained with Al2(SO4)3 and for sample 5 - lotions and shampoos production. The wastewater from UV fi lter creams production (sample 4) was resistant to treatment by DAF regardless of used coagulant. HS-SPME-GC-MS analysis can be a confirmation of DAF effectiveness
At present, industrial development is increasing pollution of soils, air and natural waters. These pollutants have a negative effect on the health and life of living organisms. Metals which interfere with the natural biological balance and inhibit self-cleaning processes in water bodies have particularly toxic effects. Cobalt, which gets into the environment from industrial sewage from electrochemical plants and the metallurgical industry, also belong to this group. This is also relatively rare and precious element, so it is important to look for additional sources of its recovery. Chemical and physicochemical methods such as: precipitation, extraction, membrane processes – nanofiltration, reverse osmosis, sorption and ion exchange are used to recover cobalt. The choice of method depends on: the kind and composition of wastewaters as well as on form and concentration of the pollutants. Ion exchange resins produced by Purolite which were used to remove cobalt ions from solutions with concentrations corresponding to its contents in galvanic wastewater was the subject of the study. It has been shown that the C 160 ion exchange resin has the best the sorption properties for Co2+ ions (54.7 mg/g). In case of this ion exchange resin, after sorption process carried out in one 50 minute cycle, cobalt concentration decreased from about 30 g/L to about 9 g/L. The values of the sorption capacity do not depend on the method of introducing the solution into an ion exchange column (pouring or dropping). E ach of the tested ion exchange resins is characterized by a high degree of cobalt concentration after regeneration using mineral acids, which can be advantageous in selecting the recovery method for this metal.
These studies examined the concept of concentration and purification of several types of wastewater by freezing and thawing. The experiments demonstrated that freezing of contaminated liquid contributed to concentration of contaminants in solution as well as significant concentration and agglomeration of solid particles. A high degree of purification was achieved for many parameters. The results of comparative laboratory tests for single and multiple freezing are presented. It was found that there was a higher degree of concentration of pollutants in wastewater frozen as man-made snow than in bulk ice. Furthermore, the hypothesis that long storage time of liquid as snow and sufficient temperature gradient metamorphism allows for high efficiency of the concentration process was confirmed. It was reported that the first 30% of the melted liquid volume contained over 90% of all impurities. It gives great opportunities to use this method to concentrate pollutants. The results revealed that the application of this process in full scale is possible. Significant agglomeration of solid particles was also noted. Tests with clay slurry showed that repeated freezing and thawing processes significantly improve the characteristics of slurry for sedimentation and filtration.
Scaling and corrosion associated with the use of natural hard water in cooling towers during recirculation pose great problems from both economical and technical points of view, such as decreased system efficiency and increased frequency of chemical cleaning. Treated municipal wastewater (MWW) is a promising alternative to freshwater as power plant cooling system makeup water, especially in arid regions. In this work, hybrid systems of salt precipitation (SP), nanofiltration (NF) and reverse osmosis (RO) were investigated, as potential pretreatment processes for wastewater reuse as cooling water in the planned Jordan nuclear power plants. The As-Samra wastewater was used to calculate the potential of carbonate and sulfate scale formation. The results were compared to scale potentials from Palo Verde wastewater. Four cases were investigated; SP, NF, SP-RO and NF-RO. The SP pretreatment cases showed the highest monovalent to divalent ratio because of a high removal of Ca and Mg and addition of Na from the chemicals of the SP step. The NF pretreatment cases, showed the lowest calcium sulfate scale potential and this potential decreases with the % pretreatment. The scale amount increases very slightly with concentration times when the SP and NF product is desalinated by RO step.
Results of the studies for determining fractions of organic contaminants in a pretreated petrochemical wastewater flowing into a pilot Aerated Submerged Fixed-Bed Biofilm Reactor (ASFBBR) are presented and discussed. The method of chemical oxygen demand (COD) fractionation consisted of physical tests and biological assays. It was found that the main part of the total COD in the petrochemical, pretreated wastewater was soluble organic substance with average value of 57.6%. The fractions of particulate and colloidal organic matter were found to be 31.8% and 10.6%, respectively. About 40% of COD in the influent was determined as readily biodegradable COD. The inert fraction of the soluble organic matter in the petrochemical wastewater constituted about 60% of the influent colloidal and soluble COD. Determination of degree of hydrolysis (DH) of the colloidal fraction of COD was also included in the paper. The estimated value of DH was about 62%. Values of the assayed COD fractions were compared with the same parameters obtained for municipal wastewater by other authors.
Azo dye wastewater treatment is urgent necessary nowadays. Electrochemical technologies commonly enable more efﬁcient degradation of recalcitrant organic contaminants than biological methods, but those rely greatly on the energy consumption. A novel process of bioﬁlm coupled with electrolysis, i.e., bioelectrochemical system (BES), for methyl orange (MO) dye wastewater treatment was proposed and optimization of main inﬂuence factors was performed in this study. The results showed that BES had a positive effect on enhancement of color removal of MO wastewater and 81.9% of color removal efﬁciency was achieved at the optimum process parameters: applied voltage of 2.0 V, initial MO concentration of 20 mg/L, glucose loads of 0.5 g/L and pH of 8.0 when the hydraulic retention time (HRT) was maintained at 3 d, displaying an excellent color removal performance. Importantly, a wide range of effective pH, ranging from 6 to 9, was found, thus greatly favoring the practical application of BES described here. The absence of a peak at 463 nm showed that the azo bond of MO was almost completely cleaved after degradation in BES. From these results, the proposed method of biodegradation combined with electrochemical technique can be an effective technology for dye wastewater treatment and may hopefully be also applied for treatment of other recalcitrant compounds in water and wastewater.
Advanced automotive fleet repair facility wastewater treatment was investigated with Zero-Valent Iron/Hydrogen Peroxide (Air/ZVI/H2O2) process for different process parameters: ZVI and H2O2 doses, time, pH. The highest Chemical Oxygen Demand (COD) removal efficiency, 76%, was achieved for ZVI/H2O2 doses 4000/1900 mg/L, 120 min process time, pH 3.0. COD decreased from 933 to 227 mg/L. In optimal process conditions odor and color were also completely removed. COD removal efficiency was increasing with ZVI dose. Change pH value below and over 3.0 causes a rapid decrease in the treatment effectiveness. The Air/ZVI/H2O2 process kinetics can be described as d[COD]/dt = −a [COD]tm, where ‘t’ corresponds with time and ‘a’ and ‘m’ are constants that depend on the initial reagent concentrations. H2O2 influence on process effect was assessed. COD removal could be up to 40% (560 mg/L) for Air/ZVI process. The FeCl3 coagulation effect was also evaluated. The best coagulation results were obtained for 700 mg/L Fe3+ dose, that was slightly higher than dissolved Fe used in ZVI/H2O2 process. COD was decreased to 509 mg/L.
The paper describes practical results of four-year laboratory studies completed to estimate technically feasible conditions of upgrading an existing sludge disposal system. A minimization of sludge mass and volume together with an energy recovery improvement were main goals of these activities. The way from lab studies and simulations to full scale investments has been shown with a special emphasis on application of respirometric procedure being applied by authors. Proposed was authors’ procedure for an estimation of a digestion time prediction for sludge of specific composition. Investigations completed at existing wastewater treatment plant resulted in practical implementation to be used during the design of upgrading and extension of the digestion and energy recovery system at the plant. It was proved that proposed changes provide close to optimum conditions for process performance and the application of proposed calculation procedures was adopted by design team
Polycyclic aromatic hydrocarbons (PAHs) constitute a large group of organic compounds that make constant threat to the environment. Their contents from natural sources are low. The processes of incomplete organic fuel combustion are the main sources of PAHs. In Upper Silesia (Poland), large amounts of PAHs are emitted into the air as a result of coal combustion in home furnaces and liquid fuel burning in combustion engines (low emission). PAHs get into surface water because of the surface runoff and point source wastewater discharges from certain industries. The following study presents PAHs concentrations in raw municipal wastewater. The tests were performed out of the heating season. The samples were collected from the combined sewer system. The analyses of PAHs were carried out with gas chromatography coupled with a mass detector (GC-MS). The concentrations of 16 PAHs sum (EPA list) ranged between 1.025 and 3.056 μg/L. Phenanthrene dominated in nearly all the analysed samples. The contents of PAHs, which are priority hazardous substances according to the directive, were high in the analysed samples. The obtained results and the analysis of diagnostic ratios for the emissions of PAHs into the air helped to reach the conclusion that traffic emissions were the main source of PAHs in the examined wastewater.
This study investigated the operation of three full-scale Lemna System surface fl ow municipal wastewater treatment plants, built according to the Lemna Corporation design. These plants consist of two ponds, the first aerated and the second for duckweed, with a barrier grid in the latter to ensure uniform plant distribution across its area. According to designers duckweed improves the efficiency of wastewater treatment. The three treatment plants are situated in central Poland and they differ in the occurrence of duckweed, two of them, located in Raków and Bąkowiec, operate without duckweed. and the third in Falęcin Stary, Lemna minor covers ca. 90% of second pond surface. The efficiency of Lemna System wastewater treatment was found not to differ between the plants with and without duckweed. The aerated pond played the main role in reduction of pollutants in the investigated Lemna Systems