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Abstract

The exploitation and processing of lignite in the Bełchatów region is connected with the formation of various mineral waste materials: varied in origin, mineral and chemical composition and raw material properties of the accompanying minerals, ashes and slags from lignite combustion and reagipsum from wet flue gas desulphurisation installations. This paper presents the results of laboratory tests whose main purpose was to obtain data referring to the potential use of fly ashes generated in the Bełchatów Power Plant and selected accompanying minerals exploited in the Bełchatów Mine in the form of self-solidification mixtures. The beidellite clays were considered as the most predisposed for use from the accompanying minerals , due to pozzolanic and sorption properties and swelling capacity. Despite the expected beneficial effects of clay minerals from the smectite group on the self-settling process as well as the stability of such blends after solidification, the results of physical-mechanical tests (compressive strength and water repellence) were unsatisfactory. It was necessary to use Ca (OH)2, obtained from the lacustrine chalk as an activator of the self-settling process It was necessary to use lacustrine chalk as an activator of the self-solidification process. The presence of calcium will allow the formation of cement phases which will be able to strongly bond the skeletal grains. Also, the addition of reagipsum to the composition of the mixture would contribute to the improvement of the physico-mechanical parameters. The elevated SO4 2– ion in the mixture during the solidification allows for the crystallization of the sulphate phases in the pore space to form bridges between the ash and clay minerals. The use of mixtures in land reclamation unfavourably transformed by opencast mining in the Bełchatów region would result in measurable ecological and economic benefits and would largely solve the problem of waste disposal from the from the operation and processing of lignite energy.
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Abstract

The transitional siliceous rocks from the Belchatow lignite deposit belong to the deposits with heterogeneous petrographic composition. The research allows us to identify among others, opoka-rocks and gaizes. The mineralogical-chemical analysis proves that the main ingredients of the studied rocks commonly used as building material are minerals of the SiO₂ group. Laboratory tests show that the nature of siliceous mineral phases has several effects on the geomechanical parameters of the studied transitional rocks. They are a reduction in water content and rock porosity, which leads to the transition of opal type A to opal type crystobalit and trydymit and then to quartz or microquartz. Their density and strength parameters are increased.
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