Nauki Techniczne

Chemical and Process Engineering: New Frontiers

Zawartość

Chemical and Process Engineering | 2016 | vol. 37 | No 4 December

Abstrakt

Straw-fired batch boilers, due to their relatively simple structure and low operating costs, are an excellent source of heat for a wide range of applications. A concept prototype of a cogeneration system with a straw-fired batch boiler was developed. The basic assumptions were based on the principles of the Rankine Cycle and the Organic Rankine Cycle systems with certain design modifications. Using the prototype design of a system that collects high-temperature heat from the boiler, studies were performed. The studies involved an analysis of the flue gas temperature distribution in the area of the oil exchanger, a comparison of the instantaneous power of the boiler’s water and oil circuits for different modes of operation, as well as an analysis of the flue gas. In the proposed system configuration where the electricity production supplements heat generation, the power in the oil circuit may be maintained at a constant level of approx. 20-30 kW. This is possible provided that an automatic fuel supply system is applied. Assuming that the efficiency of the electricity generation system is not less than 10%, it will be possible to generate 2-3 kW of electricity. This value will be sufficient, for an on-site operation of the boiler.

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Autorzy i Afiliacje

Krzysztof Sornek
Mariusz Filipowicz

Abstrakt

The work concerns the dynamic behaviour of a porous, isothermal catalyst pellet in which a simultaneous chemical reaction, diffusion and adsorption take place. The impact of the reactant adsorption onto the pellet dynamics was evaluated. A linear isotherm and a non-linear Freundlich isotherm were considered. Responses of the pellet to sinusoidal variations of the reactant concentration in a bulk gas were examined. It was demonstrated that the dynamics of the pellet is significantly affected both by accounting for the adsorption and by the frequency of the bulk concentration variations. The sorption phenomenon causes damping of the concentration oscillations inside the pellet and damping of its effectiveness factor oscillations. Depending on the frequency of the concentration oscillations in the bulk, the remarkable oscillations can involve an entire volume of the pellet or its portion in the vicinity of the external surface.

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Autorzy i Afiliacje

Katarzyna Bizon
Bolesław Tabiś

Abstrakt

Experiments on a confined fluidized bed system with various shapes of particles have been presented in the paper. Its influence on hydrodynamic properties in the whole range of gas velocity has been analysed. Relations allowing calculation of the Richardson-Zaki-type equation coefficients, including description of inter-particle void and gas pressure drop in such systems have been determined. Necessary condition for confined fluidization of non-spherical coarse particles has also been determined.

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Autorzy i Afiliacje

Bronisław Buczek
Piotr Zabierowski

Abstrakt

One of the important parameters describing pneumatic liquid atomisation is the air to liquid mass ratio (ALR). Along with the atomiser design and properties of the liquid it has extremely important influence on parameters of atomised liquid such as: mean droplet diameter, jet range and angle. Knowledge about real characteristics of an atomiser in this respect is necessary to correctly choose its operating parameters in industrial applications.

The paper presents results of experimental research of two-fluid atomisers with internal mixing built according to custom design. Investigated atomizers were designed for spraying a urea aqueous solution inside the power boiler combustion chamber. They are an important element of SNCR (selective non-catalytic reduction) installation which is used to reduce nitrogen oxides in a flue gas boiler. Obtained results were used by authors in further research, among others to determine the boundary conditions in the SNCR installation modeling.

The research included determining mean droplet diameter as a function of ALR. It has been based on the immersion liquid method and on the use of specialised instrumentation for determining distribution of droplet diameters in a spray – Spraytec by Malvern. Results obtained with both methods were later compared. The measurements were performed at a laboratory stand located at the Institute of Heat Engineering, Warsaw University of Technology. The stand enables extensive investigation of the water atomisation process.

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Autorzy i Afiliacje

Piotr Krawczyk
Krzysztof Badyda
Szczepan Młynarz

Abstrakt

The objective of the work are in-depth experimental studies of Cu(II) and Zn(II) ion removal on chitosan gel beads from both one- and two-component water solutions at the temperature of 303 K. The optimal process conditions such as: pH value, dose of sorbent and contact time were determined. Based on the optimal process conditions, equilibrium and kinetic studies were carried out. The maximum sorption capacities equaled: 191.25 mg/g and 142.88 mg/g for Cu(II) and Zn(II) ions respectively, when the sorbent dose was 10 g/L and the pH of a solution was 5.0 for both heavy metal ions. One-component sorption equilibrium data were successfully presented for six of the most useful three-parameter equilibrium models: Langmuir-Freundlich, Redlich-Peterson, Sips, Koble-Corrigan, Hill and Toth. Extended forms of Langmuir-Freundlich, Koble-Corrigan and Sips models were also well fitted to the two-component equilibrium data obtained for different ratios of concentrations of Cu(II) and Zn(II) ions (1:1, 1:2, 2:1). Experimental sorption data were described by two kinetic models of the pseudo-first and pseudo-second order. Furthermore, an attempt to explain the mechanisms of the divalent metal ion sorption process on chitosan gel beads was undertaken.

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Autorzy i Afiliacje

Józef Nastaj
Małgorzata Tuligłowicz
Konrad Witkiewicz

Abstrakt

Rotary kiln installation forms a very complex system, as it consists of various components which affect cement production. However, some problems with particle settling are encountered during operation of tertiary air installation. This paper reports on the results of a study into gas-particle flow in a tertiary air duct installation. This flow was calculated using Euler method for air motion and Lagrange method for particle motion. The results in this paper demonstrate that study focus on the tertiary air installation is a practical measure without the analysis of other processes in the rotary kiln. A solution to this problem offers several alternatives of modifying the inlet to the tertiary air duct. As a result of numerical calculations, we demonstrate the influence of geometry of a rotary kiln modification on the number of large particles transported in the tertiary air duct. The results indicate that in order to reduce large particles, rotary kiln head geometry needs to be modified, and a particle settler should be installed at its outlet.

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Autorzy i Afiliacje

Grzegorz Borsuk
Jacek Wydrych
Bolesław Dobrowolski

Abstrakt

This paper presents studies carried out in a pilot-scale plant for recovery of waste heat from a flue gas which has been built in a lignite-fired power plant. The purpose of the studies was to check the operation of the heat recovery system in a pilot scale, while the purpose of the plant was recovery of waste heat from the flue gas in the form of hot water with a temperature of approx. 90 °C. The main part of the test rig was a condensing heat exchanger designed and built on the basis of laboratory tests conducted by the authors of this paper. Tests conducted on the pilot-scale plant concerned the thermal and flow parameters of the condensing heat exchanger as well as the impact of the volumetric flow rate of the flue gas and the cooling water on the heat flux recovered. Results show that the system with a condensing heat exchanger for recovery of low-temperature waste heat from the flue gas enables the recovery of much higher heat flux as compared with conventional systems without a condensing heat exchanger.

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Autorzy i Afiliacje

Piotr Szulc
Kazimierz Wójs
Tomasz Tietze

Instrukcja dla autorów

All manuscripts submitted for publication in Chemical and Process Engineering: New Frontiers must comprise a description of original research that has neither been published nor submitted for publication elsewhere.

The content, aim and scope of the proposals have to comply with the main topics of the journal, i.e. discuss at least one of the four main areas, namely:
• New Advanced (Nano) Materials
• Environment & Water Processing (including circular economy)
• Biochemical & Biomedical Engineering (including pharmaceuticals)
• Climate & Energy (including energy conversion & storage, electrification, decarbonization)

Chemical and Process Engineering: New Frontiers publishes: i) experimental and theoretical research papers, ii) short communications, iii) critical reviews, and iv) perspective articles. Each publication form is peer-reviewed by at least two independent referees.

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1. Header details
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7. Literature citations
The method of quoting literature source in the manuscript depends on the number of its authors:
single author – their surname and year of publication should be given, e.g. Marquardt (1996) or (Marquardt, 1996),
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In the case of citing more sources in one bracket, they should be listed in alphabetical order using semicolon for separation, e.g. (Bird et al., 1960; Charpentier and McKenna, 2004; Marquardt, 1996). Should more citations of the same author(s) and year appear in the manuscript then letters “a, b, c, ...” should be successively applied after the publication year.

Bibliographic data of the quoted literature should be arranged at the end of the manuscript in alphabetical order of surnames of the first author. It is obligatory to indicate the DOI number of those literature items, whose numbers have already been assigned. Journal titles should be specified by typing their right abbreviations or, when in doubts, according to the Science and Engineering Journal Abbreviations.

Examples of citation for:

Articles
Charpentier J. C., McKenna T. F., 2004. Managing complex systems: some trends for the future of chemical and process engineering. Chem. Eng. Sci., 59, 1617-1640. DOI: 10.1016/j.ces.2004.01.044.
Information from books (we suggest adding the page numbers where the quoted information can be found)
Bird R. B., Stewart W.E., Lightfood E.N., 2002. Transport Phenomena. 2nd edition, Wiley, New York, 415-421.
Chapters in books
Hanjalić K., Jakirlić S., 2002. Second-moment turbulence closure modelling, In: Launder B.E., Sandham N.D. (Eds.), Closure strategies for turbulent and transitional flows. Cambridge University Press, Cambridge, 47-101.
Conferences
ten Cate A., Bermingham S.K., Derksen J.J., Kramer H.M.J., 2000. Compartmental modeling of an 1100L DTB crystallizer based on Large Eddy flow simulation. 10th European Conference on Mixing. Delft, the Netherlands, 2-5 July 2000, 255-264.



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Zasady etyki publikacyjnej

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Author should disclose all sources of financing of his/her study, the input of scientific institutions, associations and other subjects and all important conflicts of interests that might affect results and interpretation of the study.

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Back information
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